Introduction, History, and Overview of Applications of Piezoelectric Quartz Crystal Microbalances
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Cited by 62 publications
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The article contains sections titled: 1. Introduction to the Field of Sensors and Actuators 2. Chemical Sensors 2.1. Introduction 2.2. Molecular Recognition Processes and Corresponding Selectivities 2.2.1. Catalytic Processes in Calorimetric Devices 2.2.2. Reactions at Semiconductor Surfaces and Interfaces Influencing Surface or Bulk Conductivities 2.2.3. Selective Ion Conductivities in Solid‐State Materials 2.2.4. Selective Adsorption ‐ Distribution and Supramolecular Chemistry at Interfaces 2.2.5. Selective Charge‐Transfer Processes at Ion‐Selective Electrodes (Potentiometry) 2.2.6. Selective Electrochemical Reactions at Working Electrodes (Voltammetry and Amperometry) 2.2.7. Molecular Recognition Processes Based on Molecular Biological Principles 2.3. Transducers for Molecular Recognition: Processes and Sensitivities 2.3.1. Electrochemical Sensors 2.3.1.1. Self‐Indicating Potentiometric Electrodes 2.3.1.2. Voltammetric and Amperometric Cells 2.3.1.3. Conductance Devices 2.3.1.4. Ion‐Selective Field‐Effect Transistors (ISFETs) 2.3.2. Optical Sensors 2.3.2.1. Fiber‐Optical Sensors 2.3.2.2. Integrated Optical Chemical and Biochemical Sensors 2.3.2.3. Surface Plasmon Resonance 2.3.2.4. Reflectometric Interference Spectroscopy 2.3.3. Mass‐Sensitive Devices 2.3.3.1. Introduction 2.3.3.2. Fundamental Principles and Basic Types of Transducers 2.3.3.3. Theoretical Background 2.3.3.4. Technical Considerations 2.3.3.5. Specific Applications 2.3.3.6. Conclusions and Outlook 2.3.4. Calorimetric Devices 2.4. Problems Associated with Chemical Sensors 2.5. Multisensor Arrays, Electronic Noses, and Tongues 3. Biochemical Sensors (Biosensors) 3.1. Definitions, General Construction, and Classification 3.2. Biocatalytic (Metabolic) Sensors 3.2.1. Monoenzyme Sensors 3.2.2. Multienzyme Sensors 3.2.3. Enzyme Sensors for Inhibitors ‐ Toxic Effect Sensors 3.2.4. Biosensors Utilizing Intact Biological Receptors 3.3. Affinity Sensors ‐ Immuno‐Probes 3.3.1. Direct‐Sensing Immuno‐Probes without Marker Molecules 3.3.2. Indirect‐Sensing Immuno‐Probes using Marker Molecules 3.4. Whole‐Cell Biosensors 3.5. Problems and Future Prospects 4. Actuators and Instrumentation 5. Future Trends and Outlook
The article contains sections titled: 1. Introduction to the Field of Sensors and Actuators 2. Chemical Sensors 2.1. Introduction 2.2. Molecular Recognition Processes and Corresponding Selectivities 2.2.1. Catalytic Processes in Calorimetric Devices 2.2.2. Reactions at Semiconductor Surfaces and Interfaces Influencing Surface or Bulk Conductivities 2.2.3. Selective Ion Conductivities in Solid‐State Materials 2.2.4. Selective Adsorption ‐ Distribution and Supramolecular Chemistry at Interfaces 2.2.5. Selective Charge‐Transfer Processes at Ion‐Selective Electrodes (Potentiometry) 2.2.6. Selective Electrochemical Reactions at Working Electrodes (Voltammetry and Amperometry) 2.2.7. Molecular Recognition Processes Based on Molecular Biological Principles 2.3. Transducers for Molecular Recognition: Processes and Sensitivities 2.3.1. Electrochemical Sensors 2.3.1.1. Self‐Indicating Potentiometric Electrodes 2.3.1.2. Voltammetric and Amperometric Cells 2.3.1.3. Conductance Devices 2.3.1.4. Ion‐Selective Field‐Effect Transistors (ISFETs) 2.3.2. Optical Sensors 2.3.2.1. Fiber‐Optical Sensors 2.3.2.2. Integrated Optical Chemical and Biochemical Sensors 2.3.2.3. Surface Plasmon Resonance 2.3.2.4. Reflectometric Interference Spectroscopy 2.3.3. Mass‐Sensitive Devices 2.3.3.1. Introduction 2.3.3.2. Fundamental Principles and Basic Types of Transducers 2.3.3.3. Theoretical Background 2.3.3.4. Technical Considerations 2.3.3.5. Specific Applications 2.3.3.6. Conclusions and Outlook 2.3.4. Calorimetric Devices 2.4. Problems Associated with Chemical Sensors 2.5. Multisensor Arrays, Electronic Noses, and Tongues 3. Biochemical Sensors (Biosensors) 3.1. Definitions, General Construction, and Classification 3.2. Biocatalytic (Metabolic) Sensors 3.2.1. Monoenzyme Sensors 3.2.2. Multienzyme Sensors 3.2.3. Enzyme Sensors for Inhibitors ‐ Toxic Effect Sensors 3.2.4. Biosensors Utilizing Intact Biological Receptors 3.3. Affinity Sensors ‐ Immuno‐Probes 3.3.1. Direct‐Sensing Immuno‐Probes without Marker Molecules 3.3.2. Indirect‐Sensing Immuno‐Probes using Marker Molecules 3.4. Whole‐Cell Biosensors 3.5. Problems and Future Prospects 4. Actuators and Instrumentation 5. Future Trends and Outlook
In nature, the molecular-recognition ability of peptides and, consequently, their functions are evolved through successive cycles of mutation and selection. Using biology as a guide, it is now possible to select, tailor, and control peptide-solid interactions and exploit them in novel ways. Combinatorial mutagenesis provides a protocol to genetically select short peptides with specific affinity to the surfaces of a variety of materials including metals, ceramics, and semiconductors. In the articles of this issue, we describe molecular characterization of inorganic-binding peptides; explain their further tailoring using post-selection genetic engineering and bioinformatics; and finally demonstrate their utility as molecular synthesizers, erectors, and assemblers. The peptides become fundamental building blocks of functional materials, each uniquely designed for an application in areas ranging from practical engineering to medicine.
A Deus, por estar sempre presente e guiar o meu caminho. A minha família, por tudo que fizeram por mim e, em momento algum, deixaram de acreditar em mim, incentivando e apoiando todas as minhas escolhas. A Vanessa, minha namorada e futura esposa, que esteve comigo em todos os momentos e sempre me apoiou nas minhas decisões. Ao professor e orientador Hamilton Varela, pela orientação, dedicação e amizade que foi de grande importância para a conclusão deste trabalho. A FAPESP pelo auxílio financeiro para o meu projeto de mestrado (2016/20728-7),à CAPES e ao CNPQ.
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