“…Since the pioneer works in OPVs,16, 17, 18 rapidly increasing PCEs of OSCs are benefited from the developments of new donor/acceptor materials in the active layer and from the innovations of the device structure and geometry 19, 20, 21, 22. For example, high PCEs of 9–10% for single‐junction OSCs are achieved by combining [6,6]‐phenyl‐C71‐butyric acid methyl ester (PC 71 BM) as an acceptor with a low‐bandgap polymer, poly({4,8‐bis[(2‐ethylhexyl)oxy]benzo[1,2‐b:4,5‐b′]dithiophene‐2,6‐diyl}{3‐fluoro‐2‐[(2‐ethylhexyl)carbonyl] thieno[3,4‐b]thiophenediyl}) (PTB7) or its derivative PTB7‐Th (poly[4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐ b :4,5‐ b ′]dithiophene‐ co ‐3‐fluorothieno[3,4‐ b ]thiophene‐2‐carboxylate]) as a donor in the active layer 23, 24, 25, 26, 27.…”