Inversion of the Kirkwood–Buff theory of solutions: application to binary systems

Pandey, J. D.; Verma, Rohit

doi:10.1016/s0301-0104(01)00398-6

Cited by 43 publications

(17 citation statements)

References 9 publications

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“…Higher deviation values in PFP model can be explained as the model was developed for non-electrolyte γ-meric spherical chain molecules and the system under investigation have interacting and associating properties. Moreover, the expression used for the computation of thermal expansion coefficient, α and adiabatic compressibility,T [29] are also empirical in nature. Mixture data are presented in Table 4.…”

Section: Resultsmentioning

confidence: 99%

Pseudo-Gruneisen Parameter and Internal Pressure of Binary Mixtures from different Approaches

Shukla¹,

Gangwar²,

Shukla³

et al. 2015

Int. J. Thermo

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Density and speed of sound were measured earlier by us for binary liquid mixtures formed by Benzonitrile, Chlorobenzene, Benzyl chloride and Benzyl alcohol with Benzene at temperature range 298.15 to 313.15 K and atmospheric pressure over the whole concentration range. Pseudo-Gruneisen parameter and internal pressure were derived from the measured values of density and ultrasonic velocity. These values were compared with the theoretical values obtained by the utilization of Flory theory, Ramaswamy and Anbananthan model and model suggested by Glinski to predict the behavior of weakly interacting liquids. The observed properties derived from measured data were fitted to Redlich-Kister polynomial relation to estimate the binary coefficients and standard errors. Excess Pseudo-Gruneisen parameter for these binary mixtures was computed to study the molecular interactions involved in the liquid systems.

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Section: Resultsmentioning

confidence: 99%

Pseudo-Gruneisen Parameter and Internal Pressure of Binary Mixtures from different Approaches

Shukla¹,

Gangwar²,

Shukla³

et al. 2015

Int. J. Thermo

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“…where α A is the coefficient of thermal expansion for first component, has been obtained from a recently proposed relationship [5]. Similar expression has been employed for the computation of v * B .…”

Section: Theoreticalmentioning

confidence: 99%

“…The present investigation deals with the evaluation of thermodynamic excess functions of binary liquid mixtures at varying pressures using the formalism developed by the same. Schaaff's [4] equation and a semi-empirical formula [5] have been utilized in the calculations enabling us to evaluate excess functions directly from the density and ultrasonic velocity data only. For this purpose, five binary liquid mixtures, viz.…”

Section: Introductionmentioning

confidence: 99%

Excess functions of binary liquid mixtures at varying pressures

Pandey¹,

Soni²,

Dey³

et al. 2004

Fluid Phase Equilibria

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“…K-B theory, being a powerful tool for liquid state theory, has not received much attention in thermodynamic literature, as it deserves. Only few examples of practical applications [14][15][16][17][18][19][20][21][22][23][24][25][26][27][28] to binary mixtures can be found in which this theory has been to be used only for aqueous-alcohol 14,18−22 binary mixtures and aqueous solutions containing electrolytes. 23,24 To the best of our knowledge, very few studies have been made in the literature on nonaqueous binary mixtures.…”

Section: Introductionmentioning

confidence: 99%

Application of the Kirkwood-Buff theory of solutions to acetonitrile + amide binary mixtures by using inversion procedure and regular solution theory

Nain

2009

J Chem Sci

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The Kirkwood-Buff (K-B) integrals play an important role in characterizing the intermolecular interactions in liquid mixtures. These are represented by the K-B parameters, G AA , G BB , and G AB , which reflect correlation between like-like and like-unlike species in the mixture. The K-B integrals of binary mixtures of acetonitrile (ACN) with formamide (FA), N,N-dimethylformamide (DMF), N-methylacetamide (NMA) and N,N-dimethylacetamide (DMA) at 298⋅15 K and at atmospheric pressure have been computed from the experimental data of ultrasonic speed and density. We have used the similar inverse procedure (as proposed by Ben-Naim) to compute the K-B Parameters of the mixtures, in which thermodynamic information on mixtures such as partial molar volumes, isothermal compressibility, and experimental data of partial vapour pressures are used. A new route has been incorporated by using regular solution theory in the computation of excess free energy for obtaining the partial vapour pressures of binary liquid mixtures. The low values of excess entropy (S E ≈ 0) obtained for these mixtures indicate the applicability of regular solution theory to these mixtures. The results obtained regarding intermolecular interaction in all the four mixtures under study from this new procedure are in good agreement with those obtained from the trends exhibited by the excess functions of these mixtures.

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Inversion of the Kirkwood–Buff theory of solutions: application to binary systems

Cited by 43 publications

References 9 publications

Pseudo-Gruneisen Parameter and Internal Pressure of Binary Mixtures from different Approaches

Pseudo-Gruneisen Parameter and Internal Pressure of Binary Mixtures from different Approaches

Excess functions of binary liquid mixtures at varying pressures

Application of the Kirkwood-Buff theory of solutions to acetonitrile + amide binary mixtures by using inversion procedure and regular solution theory

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