Abstract. Quantitative knowledge of effective soil hydraulic material properties is essential to predict soil water movement.ground-penetrating radar (GPR) is a non-invasive and non-destructive geophysical measurement method to monitor the hydraulic processes precisely. Previous studies showed that the GPR signal from a fluctuating groundwater table is sensitive to the soil water characteristic and the hydraulic conductivity function. In this work, we show that this signal is suitable to accurately estimate the subsurface architecture and the associated effective soil hydraulic material properties with inversion 5 methods. Therefore, we parameterize the subsurface architecture, solve the Richards equation, convert the resulting water content to relative permittivity with the complex reflective index model (CRIM), and solve Maxwell's equations numerically. In order to analyze the GPR signal, we implemented a new heuristic event detection and association algorithm. Using events instead of the full wave regularizes the inversion as it allows to focus on the relevant measurement signal. Starting from an ensemble of Latin hypercube drawn initial parameter sets, we sequentially couple the simulated annealing algorithm with the 10 Levenberg-Marquardt algorithm. We apply the method to synthetic as well as measured data from the ASSESS test site and show that the method yields accurate estimates for the soil hydraulic material properties as well as for the subsurface architecture by comparing the results to references derived from time domain reflectometry (TDR) and subsurface architecture ground truth data.