In this work, we examine the complex structured Fractional Perturbed Gerdjikov-Ivanov Equation (FPGIE), which describes the propagation of optical pulses with perturbation effects. This model finds applications in optical fibers, especially in photonic crystal fibers. We are discovered novel and unique optical soliton solutions using the modified Extended Direct Algebraic Method (mEDAM), which has never been used with this model previously. As a result, a hierarchy of traveling wave solutions incuding singular kink, periodic, solitary kink, and rogue-shaped soliton solutions,etc., are derived. Some obtained solutions are discussed graphically based on numerical values of some parameters related to the solution. The results add new and unique soliton types to the model and demonstrate how they interact and impact the system's overall dynamics.