Investigating the diastereoselective synthesis of a macrocycle under Curtin–Hammett control

Yeung, Angus; Zwijnenburg, Martijn A.; Orton, Georgia R. F.; Robertson, Jennifer H.; Barendt, Timothy A.

doi:10.1039/d3sc05715a

Chem. Sci.

2024

DOI: 10.1039/d3sc05715a

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Investigating the diastereoselective synthesis of a macrocycle under Curtin–Hammett control

Angus Yeung,

Martijn A. Zwijnenburg,

Georgia R. F. Orton

et al.

Abstract: This work sheds new light on the stereoselective synthesis of chiral macrocycles containing twisted aromatic units, valuable π-conjugated materials for recognition, sensing, and optoelectronics. For the first time, we use...

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Cited by 2 publications

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BINOL‐Based Chiral Macrocycles and Cages

Yu,

Hu,

Ning

et al. 2024

Angewandte Chemie

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Chirality, a fundamental principle in chemistry, biology, and medicine, is prevalent in nature and in organisms. Chiral molecules, such as DNA, RNA, and proteins, are crucial in biomolecular synthesis, as well as in the development of functional materials. Among these, 1,1´‐binaphthyl‐2,2´‐diol (BINOL) stands out for its stable chiral configuration, versatile functionality, and commercial availability. BINOL is widely employed in asymmetric catalysis and chiral materials. This review mainly focuses on recent research over the past five years concerning the use of BINOL derivatives for constructing chiral macrocycles and cages. Their contributions to chiral luminescence, enantiomeric separation, transmembrane transport, and asymmetric catalysis were examined.

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BINOL‐Based Chiral Macrocycles and Cages

Yu,

Hu,

Ning

et al. 2024

Angewandte Chemie

View full text Add to dashboard Cite

show abstract

BINOL‐Based Chiral Macrocycles and Cages

Yu,

Hu,

Ning

et al. 2024

Angew Chem Int Ed

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Investigating the diastereoselective synthesis of a macrocycle under Curtin–Hammett control

Abstract: This work sheds new light on the stereoselective synthesis of chiral macrocycles containing twisted aromatic units, valuable π-conjugated materials for recognition, sensing, and optoelectronics. For the first time, we use...

Cited by 2 publications

References 91 publications

BINOL‐Based Chiral Macrocycles and Cages

BINOL‐Based Chiral Macrocycles and Cages

BINOL‐Based Chiral Macrocycles and Cages

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