Investigating the Effect of Calcine Temperature and Dwell Time on Electroluminescent Films in BCZT Ceramics

Abstract

Photoluminescent (PL) layers and electroluminescent (EL) systems have been extensively explored for constructing flat panels, screen monitors, and lighting systems. Due to their optical properties, our group is interested in the relationship between optical properties and dielectric constant is converted due to thermal change. In this study, we prepared a zinc sulfide (ZnS) fluorescent film on barium-calcium zirconium titanate ceramics. BCZT0.85 (Ba0.85Ca0.15Zr0.1Ti0.9O3) and BCZT0.9 (Ba0.9Ca0.1Zr0.1Ti0.9O3) were prepared using the solid-state reaction method for the dielectric layer. The BCZT powders were calcined at 1200 and 1250 °C and dwell times of 2 and 4h. The phase formation and microstructure characteristics were then determined using X-ray diffraction and scanning electron microscopy, respectively. The dielectric behavior and optical properties rela-tionship was then studied to determine the composition and optimal conditions for further use as thermal detectors in electric vehicle battery packs. All BCZT powders exhibited the tetragonal phase, which was confirmed by JCPDS No. 01-079-2265. The dielectric constant increased with increasing calcining temperature or dwell time. The dielectric properties showed the BCZT0.85 ceramic sintered had the maximum dielectric constant of 15342 at calcine temperature of 1250 °C for 4h. Therefore, in this study, this condition was optimal for preparing the dielectric film. The maximum dielectric constant film is 42. The electroluminescence intensity of the samples increased in a temperature-dependent manner, with the highest EL intensity at 80 °C. Moreover, the electroluminescence intensity value was enhanced with the increase of the dielectric constant. Our results show promise for developing applications for Opto-thermal sensors.