The investigation of asteroids near the Sun is important for understanding the final evolutionary stage of primitive solar system objects. A near-Sun asteroid, (155140) 2005 UD, has orbital elements similar to those of (3200) Phaethon (the target asteroid for the JAXA's DESTINY + mission). We conducted photometric and polarimetric observations of 2005 UD and found that this asteroid exhibits a polarization phase curve similar to that of Phaethon over a wide range of observed solar phase angles (𝛼 = 20−105 • ) but different from those of (101955) Bennu and ( 162173) Ryugu (asteroids composed of hydrated carbonaceous materials). At a low phase angle (𝛼 30 • ), the polarimetric properties of these near-Sun asteroids (2005 UD and Phaethon) are consistent with anhydrous carbonaceous chondrites, while the properties of Bennu are consistent with hydrous carbonaceous chondrites. We derived the geometric albedo, 𝑝 V ∼ 0.1 (in the range of 0.088−0.109); mean 𝑉-band absolute magnitude, 𝐻 V = 17.54 ± 0.02; synodic rotational period, 𝑇 rot = 5.2388 ± 0.0022 hours (the two-peaked solution is assumed); and effective mean diameter, 𝐷 eff = 1.32 ± 0.06 km. At large phase angles (𝛼 80 • ), the polarization phase curve are likely explained by the dominance of large grains and the paucity of small micron-sized grains. We conclude that the polarimetric similarity of these near-Sun asteroids can be attributed to the intense solar heating of carbonaceous materials around their perihelia, where large anhydrous particles with small porosity could be produced by sintering.