Investigation into the nature and chemistry of thiazyl chloride monomer and trimer (NSCL)n (n = 1,3) in solution using nitrogen-14 NMR spectroscopy, a useful routine tool for the characterization of small sulfur-nitrogen-containing compounds

The preparation of 1,2,3,5-dithiadiazolium chlorides from the reaction of nitrile sulphides with thiazyl chloride

“…The thiazyl chloride monomer is known to be intimately involved with its trimer (NSCl), in solution and it has been reported using I4N NMR spectroscopy that the equilibrium between the monomer and the trimer is strongly dependant on the solvent polarity and temperature (8). We have shown using 1 4~ NMR that the trimer is soluble in chlorobenzene and that at room temperature only trace amounts of the monomer can be detected.…”

“…Thiazyl halides (N=S-X, X = F, C1) are well known in sulphur-nitrogen chemistry for their high reactivity and predictable behaviour in cycloaddition reactions (8,18). A number of methods have been reported for the generation of these species (19).…”

The metathesis reactions of [SNS][SbF6] and [SN][AsF6] with Li[Al(OC(CF3)3)4] in liquid SO2

“…Only all nonfluorine atoms were refined anisotropically due to lack of data. All figures illustrating structures were prepared using the program Diamond (8): S1-N1 1.469 (10), S2-N1 1.498 (10), and S1-N1-S2 178.1 (8).…”

Substituted 1,3,2,4‐benzodithiadiazines: Novel derivatives, by‐products, and intermediates*

“…The 14 N NMR identification of NSCl (δ 14 N: 730) was based on previously reported data [33] and on control measurements with an authentic sample prepared [33] by heating a solution of (NSCl) 3 [34] in CCl 4 . At the same time, (NSCl) 3 [33,35] was not found in the reaction mixtures in accordance with the conclusion that trimerization of NSCl is very ki-netically hindered [33].…”