Investigation of catalytic potential of sodium dodecyl sulfate stabilized silver nanoparticles for the degradation of methyl orange dye

Naseem, Khalida; Ali, Faisal; Tahir, Mudassir Hussain; Afaq, Muhammad; Yasir, Hafiz Muhammad; Ahmed, Khalil; Aljuwayid, Ahmed Muteb; Habila, Mohamed A.

doi:10.1016/j.molstruc.2022.132996

Cited by 47 publications

(25 citation statements)

References 60 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The dispersion results in complexed cross-linkages between water and sulfate ions, which can be further converted to nanosized particles, as a result of interaction between sodium dodecyl and water upon adjustment of pH. This interaction results in the formation of micelles, then converted to nanosize SDS particles, as reported by Naseem and her peers . The Ag–Cu BNPs were fabricated using the chemical reduction method in which silver and copper solutions were added one by one to reaction mixture containing SDS colloidal particles that had sulfate ions.…”

Section: Resultsmentioning

confidence: 95%

“…This interaction results in the formation of micelles, then converted to nanosize SDS particles, as reported by Naseem and her peers. 39 The Ag−Cu BNPs were fabricated using the chemical reduction method in which silver and copper solutions were added one by one to reaction mixture containing SDS colloidal particles that had sulfate ions. The stabilization of both the nanoparticles (Ag−Cu BNPs and SDS NPs) were interlinked with each other by the embedding of Ag−Cu BNPs on SDS-NPs due to the interaction between Ag−Cu + with negative charged sulfate ions and reduced using NaBH 4 to fine bimetallic nanoparticles within same unit studies are similar to Aazam and his co-workers.…”

Section: Resultsmentioning

confidence: 99%

“…The graph is linear, which means the degradation increases with increase in Ag−Cu BNPs concentration or in other words, all the sites at the surface of nanocatalyst were available for substrate and NaBH 4 , leads to increase in degradation. 39 Figure 9i shows the speed of MO degradation in terms of k exp vs BNPs different concentrations.…”

Section: Xrd Analysismentioning

confidence: 99%

See 2 more Smart Citations

Ag–Cu Embedded SDS Nanoparticles for Efficient Removal of Toxic Organic Dyes from Water Medium

Ali

Mehmood

Ashraf

et al. 2023

Ind. Eng. Chem. Res.

Self Cite

View full text Add to dashboard Cite

Remediation of industrial water pollution is a trending subject to date for the researchers around the globe, due to its detrimental effects on human life as well as aquatic life. Azo dyes are the largest industrial water polluters in respect of volume while anthraquinone the second largest. Therefore, humongous considerations are being enumerated for the removal and decolorization of azo (AZ) dyestuff; however, for anthraquinone (AQ) dyes, these efforts are considerably minimal; although the later one poses a greater threat to environmental contamination, because of their reinforced structure. The current study is an effort toward this foremost issue. Chemical reduction synthesis of silver−copper (Ag−Cu) bimetallic nanoparticles (BNPs) was achieved using NaBH 4 as a reducing agent and sodium dodecyl sulfate (SDS) as a stabilizer. Characterization and morphological evaluation indicates two distinctive UV/vis absorption peaks for Ag and Cu. XRD studies for nanocomposite showed crystallite size of 8.96014 nm having an FCC structure. SEM with EDX confirmed the particle sizes of BNPs and SDS to be 17.14 and 114.56 nm, respectively. Potential catalytic activity and kinetic parameters of Ag−Cu BNPs@SDS were monitored against Methylene Blue (MB), Methyl Orange (MO), and eosin-y (EY). The percentage degradation recorded for the nanocatalyst against MO, MB, and EY was 95.21%, 98.57%, and 96.65%, respectively. This method can be adopted for the removal of multiple dyes from industrial effluent on a larger scale.

show abstract

Section: Resultsmentioning

confidence: 95%

Section: Resultsmentioning

confidence: 99%

See 1 more Smart Citation

Ag–Cu Embedded SDS Nanoparticles for Efficient Removal of Toxic Organic Dyes from Water Medium

Ali

Mehmood

Ashraf

et al. 2023

Ind. Eng. Chem. Res.

Self Cite

View full text Add to dashboard Cite

show abstract

“…Similar to the catalytic reduction of 4-NP, our AgNPs exhibit a similar behavior, i.e., AgNP1 demonstrating an induction period of ∼150 s while the catalytic reduction of MO begins immediately upon the addition AgNP2 . Nevertheless, both m NHC-tethered AgNPs exhibit relatively similar higher reduction rate constants compared to those stabilized by sodium dodecyl sulfate, tannic acid, and citrate groups as well as Pd–Au bimetallic alloy nanoparticles for the catalytic degradation of MO. We examined the recyclability of AgNPs.…”

Section: Resultsmentioning

confidence: 97%

Monomeric and Polymeric Mesoionic N-Heterocyclic Carbene-Tethered Silver Nanoparticles: Synthesis, Stability, and Catalytic Activity

et al. 2023

View full text Add to dashboard Cite

In recent years, N-heterocyclic carbenes (NHCs) have garnered significant attention as promising alternatives to thiols to stabilize metallic nanoparticles and planar surfaces. While most studies thus far have focused on NHC-functionalized gold nanoparticles (AuNPs), as an ideal platform to investigate the role of NHCs in stabilizing such nanoparticles, their ability to protect more unstable coinage metal nanoparticles, such as silver nanoparticles (AgNPs), has been largely overlooked. This is despite the fact that AgNPs possess a much more sensitive optical response that, upon their enhanced stability, can broaden their scope of application in various fields, including nanomedicine and catalysis. In this study, the synthesis and use of monomeric and polymeric mesoionic NHC–Ag(I) complexes as precursors to mono- and multidentate NHC-tethered AgNPs are reported. The polymeric analog was obtained by first synthesizing a polymer, containing 1,2,3-triazole repeat units, employing the copper-catalyzed alkyne–azide cycloaddition click polymerization of monomers containing diazide- and dialkyne functional groups. Subsequent quaternization of the triazole moieties and Ag insertion yielded the target NHC–Ag-containing polymer. Using this polymer as well as its monomeric analog as substrates, AgNPs with either catenated networks of NHCs or monomeric NHCs were fabricated by their reduction using borane–tert-butylamine complex. Our stability studies demonstrate that while monomeric NHCs impart some degree of stability to AgNPs, particularly at elevated temperatures in aqueous as well as organic medium, their polymeric analogs further enhance their stability in acidic environment (pH = 2) and against glutathione (3 mM), as an example of a biologically relevant thiol, in aqueous media. To highlight the application of these NHC-functionalized AgNPs in catalysis, we explore the aqueous phase reduction of methyl orange and 4-nitrophenol.

show abstract

“…26,27 On the other hand, the incorporation of nanoparticles such as ZnO/Ag and phenyldiazene-based metal complexes in nonwoven composites can improve their UV shielding, antibacterial, and antifungal properties. 28,29…”

Section: Introductionmentioning

confidence: 99%

Development and application of nonwovens based on palm fiber as reinforcements of unsaturated polyester

Azmami

Sajid

Majid

et al. 2022

Journal of Composite Materials

View full text Add to dashboard Cite

This work aims to investigate the potential of nonwovens made from untreated (U) and alkaline/bleaching treated (T) palm, wool, and polyester fibers as reinforcing materials in polyester matrix for automotive interior applications. Four needle-punched nonwovens were developed and used with and without chloropropyltriethoxysilane (CPTS) treatment as polyester matrix fillers. Eight composite panels were made using the resin transfer molding machine process and compared to the matrix panel in terms of physical, mechanical, thermal, and climate resistance. The produced composite materials have smooth surfaces and provide consumers with four different aesthetically pleasing finishes. The physical results reveal that the UPalm/Wool and UPalm/Polyester nonwovens lower matrix density from 1223.3 Kg/m3 to 1022.3 and 1040.7 Kg/m3, respectively. The SEM images show that palm fibers are more adherent to the matrix after being treated with an alkaline/bleaching solution. This adhesion is also improved after nonwovens are treated with the CPTS precursor. The composite reinforced with CPTS-treated TPalm/Polyester nonwoven has the highest tensile strength and modulus (72.1 MPa and 3.76 GPa), which are 127% and 36% greater than those of the polyester matrix, respectively. The matrix’s flexural strength and modulus are also enhanced by 148% and 59%, respectively, after reinforcing with CPTS-treated TPalm/Polyester nonwoven. The use of TPalm/Wool and TPalm/Polyester nonwovens as polyester matrix fillers reduces their thermal conductivity from 0.125 W/(m.K) to 0.081 and 0.095 W/(m.K), respectively. Moreover, the climate aging results indicate that composites reinforced with CPTS-treated nonwovens are more stable to climate, implying their applicability and durability in automotive interior applications.

show abstract

Investigation of catalytic potential of sodium dodecyl sulfate stabilized silver nanoparticles for the degradation of methyl orange dye

Cited by 47 publications

References 60 publications

Ag–Cu Embedded SDS Nanoparticles for Efficient Removal of Toxic Organic Dyes from Water Medium

Ag–Cu Embedded SDS Nanoparticles for Efficient Removal of Toxic Organic Dyes from Water Medium

Monomeric and Polymeric Mesoionic N-Heterocyclic Carbene-Tethered Silver Nanoparticles: Synthesis, Stability, and Catalytic Activity

Development and application of nonwovens based on palm fiber as reinforcements of unsaturated polyester

Contact Info

Product

Resources

About