1999
DOI: 10.1016/s0038-1098(99)00008-3
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Investigation of Cr3+ ions in Cs2NaGaF6 single crystals by optical spectroscopy

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Cited by 51 publications
(31 citation statements)
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“…Cs 2 NaAlF 6 and Cs 2 NaGaF 6 crystals, doped with approximately 0.1 atomic % Cr 3+ , were hydrothermally grown [4,5]. X (9.57 GHz) and Q-band (34.0 GHz) EPR and ENDOR spectra were recorded at 20 K on a Bruker ESP300E spectrometer with ESP353 ENDOR/Triple extension, and a Bruker ELEXSYS E500 spectrometer, respectively.…”
Section: Resultsmentioning
confidence: 99%
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“…Cs 2 NaAlF 6 and Cs 2 NaGaF 6 crystals, doped with approximately 0.1 atomic % Cr 3+ , were hydrothermally grown [4,5]. X (9.57 GHz) and Q-band (34.0 GHz) EPR and ENDOR spectra were recorded at 20 K on a Bruker ESP300E spectrometer with ESP353 ENDOR/Triple extension, and a Bruker ELEXSYS E500 spectrometer, respectively.…”
Section: Resultsmentioning
confidence: 99%
“…The hexagonal elpasolite crystals Cs 2 NaMF 6 (M = Al, Ga) are in this respect particularly interesting, because they allow high Cr 3+ doping concentrations. Previous optical [4,5] and electron paramagnetic resonance (EPR) [6,7] studies have shown that Cr 3+ can be incorporated on two crystallographic positions in hexagonal Cs 2 NaMF 6 lattices, which have been proposed to correspond to the two inequivalent M 3+ sites [8,9], shown in Fig. 1.…”
Section: Introductionmentioning
confidence: 99%
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“…[4]. The crystallographic details for the host lattices are available [15][16][17]. All compounds have a cubic elpasolite-type structure and crystallize in the space group Fm3m, except for Cs 2 NaGaF 6 which has the rhombohedral 12L-type crystal structure and belongs to the space group R-3m.…”
Section: Introductionmentioning
confidence: 99%
“…Cr 3þ ion in fluoride crystals have been investigated by several research groups [6,7] since laser action in KZnF 3 :Cr 3þ was obtained for the first time [8].…”
Section: Introductionmentioning
confidence: 99%