Investigation of crystal structure and associated electronic structure of Sr6BP5O20

Ehrenberg, Helmut; Laubach, Sonja; Schmidt, Peter; McSweeney, Robert T.; Knapp, Michael; Mishra, K. C.

doi:10.1016/j.jssc.2005.12.033

Cited by 23 publications

(12 citation statements)

References 9 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The correct chemical formula was deduced by Smets [21] to be Sr 6 B(PO 4 ) 5 on the basis of the lattice vectors and comparison to Sr 2 P 2 O 7 . Based on synchrotron powder diffraction and single crystal data, a complete structure model was derived and reported [22,23]. Here we are replacing boron by aluminum to get Sr 6 AlP 5 O 20 and then Sr 2 + by Ca 2 + , Ba 2 + and Mg 2 + ions (alkali earth metals).…”

Section: Xrd Patterns Of X 6 Alp 5 O 20 (Where X ¼Sr/ba/ca/mg) New Mamentioning

confidence: 99%

Synthesis of novel Dy3+ activated phosphate phosphors for NUV excited LED

Shinde¹,

Dhoble

Kumar

2011

Journal of Luminescence

View full text Add to dashboard Cite

Section: Xrd Patterns Of X 6 Alp 5 O 20 (Where X ¼Sr/ba/ca/mg) New Mamentioning

confidence: 99%

Synthesis of novel Dy3+ activated phosphate phosphors for NUV excited LED

Shinde¹,

Dhoble

Kumar

2011

Journal of Luminescence

View full text Add to dashboard Cite

“…As displayed in the bottom inset of Figure , by extrapolating the value of h ν to the photo energy axis linearly, the obtained E g value is 5.56 eV. It is generally accepted that the DFT calculation may underestimate the band gap in some ways, so the experimental value of the band gap corresponds with the calculated value. ,, …”

Section: Resultsmentioning

confidence: 70%

A Garnet-Based Ca₂YZr₂Al₃O₁₂:Eu³⁺ Red-Emitting Phosphor for n-UV Light Emitting Diodes and Field Emission Displays: Electronic Structure and Luminescence Properties

et al. 2016

View full text Add to dashboard Cite

A series of CaYZrAlO:Eu (CYZA) phosphors were successfully synthesized through conventional solid-state method. The electronic structure and their photoluminescence or cathodoluminescence properties were investigated in detail. Under n-UV excitation, the CYZA:Eu exhibits more intense red emission than the commercial YO:Eu phosphor. A WLED lamp with good color render index was obtained by fabricating the phosphor with BAM:Eu and LuAG:Ce phosphors. The phosphor also exhibits red emission with high current saturation and high resistance under low voltage electron bombardment. The degradation resistance can be compared to the commercial YO:Eu phosphor. All the results indicate that the CYZA:Eu has potential applications in both white LEDs and FEDs.

show abstract

“…The Na 3 PbO 4 units, together with the other “propeller-like” oligomeric anionic unit [B(O 3 POH) 4 ] 5– , form layers perpendicular to the [001] direction. The oligomeric FBUs are reported to occur in M 9 [BP 4 O 16 ][PO 4 ] (M = Pb, Sr) structures without protonation. , The hydroxyl group on the PO 4 tetrahedron, however, may open a way to further condensation. Another lead-containing borophosphate prepared hydrothermal is Pb II 4 {Co 2 [B(OH) 2 P 2 O 8 ](PO 4 ) 2 ]}Cl .…”

Section: Synthesismentioning

confidence: 99%

New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates

Li¹,

Verena‐Mudring

2016

Crystal Growth & Design

View full text Add to dashboard Cite

An overview about the recent key developments of borophosphate chemistry since 2007 is given. The structural chemistry (B:P ratio, fundamental building units (FBUs), dimensionality and metal coordination), possible physical, and optical and chemical properties are discussed in detail in terms of materials obtained by traditional solid-state reactions, flux methods, and hydrothermal and ionothermal reactions. Borophosphates (BPOs) exhibit a tremendous structural variety. Which structure is formed depends critically on the chosen starting materials and synthetic conditions. For example, for metalloborophosphates (MBPOs) changing the metal-precursor can result in the formation of a new BPO. MBPOs containing chains or extended networks of interconnected transition metal-oxide polyhedra exhibit remarkable magnetic coupling schemes and electronic behavior aside from interesting optical behavior and catalytic properties. The exploration of novel fundamental building units (FBUs), such as FBUs with P−O− P bonds and two-dimensional mixed-coordinated anionic partial structures, that have not been observed previously advocates the great potential in designing novel functional BPOs for advanced applications. While many BPOs initially obtained from conventional synthetic methods can be prepared by hydrothermal synthesis, it has recently been realized that BPOs obtained by ionothermal methods often could not be synthesized by conventional synthetic methods. Thus, novel synthetic approaches offer access to new materials.

show abstract

Investigation of crystal structure and associated electronic structure of Sr6BP5O20

Cited by 23 publications

References 9 publications

Synthesis of novel Dy3+ activated phosphate phosphors for NUV excited LED

Synthesis of novel Dy3+ activated phosphate phosphors for NUV excited LED

A Garnet-Based Ca₂YZr₂Al₃O₁₂:Eu³⁺ Red-Emitting Phosphor for n-UV Light Emitting Diodes and Field Emission Displays: Electronic Structure and Luminescence Properties

New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates

Contact Info

Product

Resources

About

Investigation of crystal structure and associated electronic structure of Sr6BP5O20

Cited by 23 publications

References 9 publications

Synthesis of novel Dy3+ activated phosphate phosphors for NUV excited LED

Synthesis of novel Dy3+ activated phosphate phosphors for NUV excited LED

A Garnet-Based Ca2YZr2Al3O12:Eu3+ Red-Emitting Phosphor for n-UV Light Emitting Diodes and Field Emission Displays: Electronic Structure and Luminescence Properties

New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates

Contact Info

Product

Resources

About

A Garnet-Based Ca₂YZr₂Al₃O₁₂:Eu³⁺ Red-Emitting Phosphor for n-UV Light Emitting Diodes and Field Emission Displays: Electronic Structure and Luminescence Properties