This study examines the high-frequency-dependent characteristics of the PbO/SnO 2 double-layer semiconductor (DLS) structures. Recently, researchers have been particularly interested in such structures in terms of their use in electrical and photovoltaic applications. A PbO/SnO 2 double layer was successfully coated on a p-type Si substrate (100) wafer with a resistance of 10 Ω cm and a thickness of 280 μm. The Al Schottky (round dot) connections, which have a thickness of 124 nm and a diameter of 1.3 mm, were produced by thermal evaporation. The present study proposes to measure the conductance−voltage (G−V) and capacitance−voltage (C−V) values of the studied Al/PbO/SnO 2 /p-Si Schottky diode for the frequencies of 500 kHz, 800 kHz, and 1 MHz at a temperature of 300 K, which has been suggested for the first time in literature. Due to the presence of surface states (N ss ), PbO/SnO 2 double-layer, and series resistance R s , the C−V and G−V plots show inversion, depletion, and accumulation zones depending on the strong frequency for each frequency tested. Based on the tested frequencies, the reverse-biased C 2 −V curves are used to compute the fundamental electrical characteristics of the Al/PbO/SnO 2 /p-Si structures, including the depletion layer (W D ), Fermi energy level (E F ), diffusion potential (V D ), and thickness barrier height (⌀ B ). We also investigated the capacitance features and the energy density distribution of surface states (N ss ) in the PbO/SnO 2 double-layer structure by utilizing the measured values of G−V and C−V. The values of ⌀ B , V D , and N ss were observed to be 0.54 0.34, and 3.19 10 12 eV −1 cm −2 at 500 kHz, while they were 0.88 0.68, and 1.96 eV −1 cm −2 at 800 kHz and 0.95, 0.75, and 1.47 eV −1 cm −2 at 1 MHz, respectively. It was discovered that the capacitance characteristics of the PbO/SnO 2 double-layer structure were substantially dependent on the applied high frequencies. Furthermore, the C−V and G−V measurements revealed that the series resistance and the interface state density of the studied Al/PbO/SnO 2 /p-Si Schottky diode were critical parameters that significantly affect the electrical parameters offered by the PbO/SnO 2 double-layer nanostructure. The results of the study reveal that the manufactured device exhibits outstanding electric characteristics and support the possibility of using DL thin films in electronic devices.