Abstract:A facile, rapid and sensitive catalytic hydrogen signal method has been developed for the analysis of chromium(VI) using two new ligands Ammonium N-phenylpiperazine-1-carbodithioate (APP-CDT) and Ammonium N-benzylpiperidine-1-carbodithioate (ABP-CDT) were synthesized. The method was depending on the reaction of chromium(VI) with APP-CDT and ABP-CDT at pH 8.6 and 7.8 respectively in supporting electrolyte (NH 4 Cl-NH 4 OH) medium. The resulting oxidation peaks were obtained at -1.68V and -1.60 V vs SCE respecti… Show more
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