Investigation of electrochemical copolymerisation of hydroxmethyl substituted 3,4-ethylenedioxythiophene with bithiophene

Golba, Sylwia; Łężniak, Marta; Gabor, Jadwiga; Flak, Tomasz

doi:10.1016/j.synthmet.2014.11.029

Cited by 6 publications

(3 citation statements)

References 64 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…It's worth noting that most electropolymerization systems are limited to organic solvents [11,[20][21][22][23][24], which exhibit some shortcomings such as environmental pollution, insecurity, energy shortage etc. Aqueous solution, as a promising "green" alternative solvent medium to traditional volatile and toxic solvents, is beneficial from a cost, handling, environmentally friendly, and safety point of view.…”

Section: Introductionmentioning

confidence: 99%

Aqueous electrosynthesis of an electrochromic material based water-soluble EDOT-MeNH2 hydrochloride

et al. 2016

View full text Add to dashboard Cite

. (2016). Aqueous electrosynthesis of an electrochromic material based water-soluble EDOT-MeNH2 hydrochloride. Synthetic Metals, 211 147-154. Aqueous electrosynthesis of an electrochromic material based watersoluble EDOT-MeNH2 hydrochlorideAbstract 2'-Aminomethyl-3,4-ethylenedioxythiophene (EDOT-MeNH2) showed unsatisfactory results when its polymerization occurred in organic solvent in our previous report. Therefore, a water-soluble EDOT derivative was designed by using hydrochloric modified EDOT-MeNH2 (EDOT-MeNH2·HCl) and electropolymerized in aqueous solution to form the corresponding polymer with excellent electrochromic properties. Moreover, the polymer was systematically explored, including electrochemical, optical properties and structure characterization. Cyclic voltammetry showed low oxidation potential of EDOT-MeNH2·HCl (0.85 V) in aqueous solution, leading to the facile electrodeposition of uniform the polymer film with outstanding electroactivity. Compared with poly(2′-aminomethyl-3,4-ethylenedioxythiophene) (PEDOTMeNH2), poly(2′-aminomethyl-3,4-ethylenedioxythiophene salt) (PEDOT-MeNH3 +A-) revealed higher efficiencies (156 cm2 C-1), lower bandgap (1.68 eV), and faster response time (1.4 s). Satisfactory results implied that salinization can not only change the polymerization system, but also adjust the optical absorption, thereby increase the electrochromic properties.

show abstract

Section: Introductionmentioning

confidence: 99%

Aqueous electrosynthesis of an electrochromic material based water-soluble EDOT-MeNH2 hydrochloride

et al. 2016

View full text Add to dashboard Cite

show abstract

“…Absorbance bands at 836 and 976 cm −1 have been assigned to the stretching of the C-S bond of the thiophene ring. 49,[64][65][66][67][68][69] Stretching vibrations within the ethyelenedioxy ring absorb at 1062, 1104, 1220 cm −1 . 64,[66][67][68][69][70][71][72][73][74] Several IR peaks can be traced to the stretching of the C=C and C-C bonds within the thiophene ring at 1169, 1370, 1477, and 1525 cm −1 .…”

Section: Resultsmentioning

confidence: 99%

“…49,[64][65][66][67][68][69] Stretching vibrations within the ethyelenedioxy ring absorb at 1062, 1104, 1220 cm −1 . 64,[66][67][68][69][70][71][72][73][74] Several IR peaks can be traced to the stretching of the C=C and C-C bonds within the thiophene ring at 1169, 1370, 1477, and 1525 cm −1 . 49,67,68,[70][71][72][73]75 The bending vibration of H 2 O molecules retained within the film and the stretching of the C=O bond within the ester of monomer 2 absorb at 1642 and 1739 cm −1 , respectively.…”

Section: Resultsmentioning

confidence: 99%

Spatially Directed Functionalization by Co-electropolymerization of Two 3,4-ethylenedioxythiophene Derivatives on Microelectrodes within an Array

Jones

Korzeniewski

Franco

et al. 2020

J. Electrochem. Soc.

View full text Add to dashboard Cite

Electrodeposited conductive copolymer films with predictable relative properties (quantities of functional groups for further modification and capacitance) are of interest in sensors, organic electronic materials and energy applications. Potentiodynamic copolymerization of films in aqueous solutions of two different thiophene derivatives, (2,3-dihydrothieno[3,4-b]dioxin-2-yl)methanol (1) and 4-((2,3-dihydrothieno[3,4-b][1,4]dioxin-2-yl)-methoxy)-4-oxobutanoic acid (2), containing 0.02 M total monomer (0, 25, 34, 50, 66, 75, 100 mol% 2), 0.05 M sodium dodecyl sulfate, and 0.1 M LiClO4, on gold microelectrodes in an array was investigated. Decreasing monomer deposited (m) from 0 to 100 mol% 2 is attributed to a decreasing pH that inhibits electropolymerization. Molar ratios of 1 and 2 in the films, determined by micro-attenuated total reflectance Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy, tracks closely with the ratio in the deposition solutions. Capacitances measured from cyclic voltammetry in aqueous buffer and electron transfer of ferrocyanide at the films are unaffected by copolymer composition, except for the 100 mol% 2 case. Ratios of reverse-to-forward faradaic peak currents suggest that films with high content of 1 expand in the anodic form and contract in the cathodic form and vice versa for films with high content of 2, where anions and cations dominate counterion transport from solution, respectively.

show abstract

Multi-color electrochromic copolymer films based on 2,2′-thiophene and 3, 4-ethylenedioxythiophen

Zeng,

Wu,

et al. 2024

Synthetic Metals

View full text Add to dashboard Cite

Investigation of electrochemical copolymerisation of hydroxmethyl substituted 3,4-ethylenedioxythiophene with bithiophene

Cited by 6 publications

References 64 publications

Aqueous electrosynthesis of an electrochromic material based water-soluble EDOT-MeNH2 hydrochloride

Aqueous electrosynthesis of an electrochromic material based water-soluble EDOT-MeNH2 hydrochloride

Spatially Directed Functionalization by Co-electropolymerization of Two 3,4-ethylenedioxythiophene Derivatives on Microelectrodes within an Array

Multi-color electrochromic copolymer films based on 2,2′-thiophene and 3, 4-ethylenedioxythiophen

Contact Info

Product

Resources

About