With the global production
of 150 million tons in 2016, ethylene
is one of the most significant building blocks in today’s chemical
industry. Most ethylene is now produced in cracking furnaces by thermal
cracking of fossil feedstocks with steam. This process consumes around
8% of the main energy used in the petrochemical industry, making it
the single most energy-intensive process in the chemical industry.
This paper studies a tubular thermal cracking reactor fed by propane
and the molecular mechanism of the reaction within the reactor. After
developing the reaction model, the existing issues, such as the reaction,
flow, momentum, and energy, were resolved by applying heat to the
outer tube wall. After solving the entropy generation equations, the
entropy generation ratio of the sources was evaluated. The temperature
of the tube/reactor was tuned following the reference results, and
processes were replicated for different states. The verification of
the modeling and simulation results was compared with the industrial
case. The Genetic Programming (GP) machine learning approach was employed
to generate objective functions based on key decision variables to
reduce the computational time of the optimization algorithm. For the
first time, this study has proposed a systematic approach for optimizing
a thermal cracking reactor based on a combination of Genetic Programming
(GP), Water Cycle Algorithm (WCA), and Genetic Algorithm (GA). In
this regard, multiobjective optimization was performed based on the
maximization of the products and entropy generation with the generation
of GP objective functions. The key decision variables in this study
included inlet gas temperature, inlet gas pressure, air mass flow
rate, and wall temperature. The results showed that the weighted percentage
of products after optimization increased to 61.13% and the entropy
production rate of the system decreased to 899.80 J/s, displaying
an improvement of 0.85 and 16.51% compared with the base case, respectively,
with the multiobjective GA algorithm. In addition, by applying the
multiobjective WCA, the weighted percentage of products increased
to 61.81%. The entropy production rate of the system decreased to
882.72 J/s. So, an improvement of 1.97% in weights of products and
an improvement of 18.77% in entropy generation have been achieved
compared with the base case.