This paper presents the analysis of optical emission spectroscopic measurements from vacuum ultraviolet (120 nm) to near infrared (960 nm) in a high-enthalpy air plasma flow corresponding to superorbital reentry conditions. The vacuum ultraviolet measurements have been realized with a new experimental setup allowing measurements through a bore hole in the sample. Using the commonly applied optical emission spectroscopy from the side, the radiation transport along the line of sight of the vacuum ultraviolet measurements has been assessed. This allowed the determination of the local ground state densities of atomic oxygen and atomic nitrogen from a branching ratio analysis and the blackbody limiting correction of the vacuum ultraviolet radiation. Through the analysis of the absorption in the borehole, the spectra have been corrected, resulting in a stagnation point radiative heat flux in the vacuum ultraviolet of 235 kW∕m 2 .= local mass-specific enthalpy, MJ∕kg I = arc current, A K = proportionality constant for air, W∕MJ∕kg·Pa 0.5 ·m 1.5 k = Boltzmann constant, J∕K k cal = calibration factor, W∕m 2 · nm · sr∕counts∕s L λ = spectral radiance, W∕m 2 · nm · sr L λ;Limit = blackbody limit spectral radiance, W∕m 2 · nm · sr M = magnification _ m = mass flow, g∕s n = number density, m −3 n i = excited state population density, m −3 n 0 = ground state population density, m −3 P = electric power, kW P k = spectral line shape, nm −1 p = pressure, hPa _ q = heat flux, kW∕m 2 R eff = effective nose radius, mm r = radial distance, mm S = raw signal, counts/s s = distance from the probe surface, mm s 0 = distance between object and focusing element, mm= vibrational quantum number x = axial distance from the nozzle, mm y = horizontal distance from the nozzle, mm z = vertical distance from the nozzle, mm α λ = absorption coefficient, m −1 δ = full width at half-maximum of line broadening, nm ε λ = emission coefficient, W∕m 3 · nm · sr ε = spectrally integrated emission coefficient, W∕m 3 · sr λ = wavelength, nm σ λ = absorption cross section, m 2 Subscripts BB = blackbody DL = deuterium lamp exc = electronic excitation IS = integrating sphere l = lower state rot = rotational tot = total trans = translational u = upper state vib = vibrational