Currently, almost
all polymer optical materials are derived from
fossil resources with known consequences for the environment. In this
work, a processing route to obtain cellulose-based biopolymer optical
fibers is presented. For this purpose, the optical properties such
as the transmission and the refractive index dispersion of regenerated
cellulose, cellulose diacetate, cellulose acetate propionate, and
cellulose acetate butyrate were determined from planar films. Cellulose
fibers were produced using a simple wet-spinning setup. They were
examined pure and also coated with the cellulose derivatives to obtain
core–cladding-structured optical fibers. The cellulose-based
optical fibers exhibit minimum attenuations between 56 and 82 dB m–1 at around 860 nm. The ultimate transmission loss
limit of the cellulose-based optical fibers was simulated to characterize
the attenuation progression. By reducing extrinsic losses, cellulose-based
biopolymer optical fibers could attain theoretical attenuation minima
of 84.6 × 10–3 dB m–1 (507
nm), 320 × 10–3 dB m–1 (674
nm), and 745.2 × 10–3 dB m–1 (837 nm) and might substitute fossil-based polymer optical fibers
in the future.