Investigation of Ionic Liquids as Extraction Solvents for Separating Bicyclic Aromatic S/N-Compounds from FCC Diesel

Abstract

To improve the quality of fluid catalytic cracking (FCC) diesel, ionic liquids (ILs) were used as promising neoteric solvents to extract bicyclic S/N-compounds (quinoline and 1-benzothiophene) from FCC model oil. In addition to the thermodynamic properties, including solvent capacity and selectivity, physical properties such as viscosity and thermal stability are also considered as important factors in the IL screening process. 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C2MIM][NTF2]) was selected as the most suitable extraction solvent by the COSMO-RS model, and the accuracy of this model was verified based on the collected experimental data. Liquid–liquid equilibrium experiments were performed to study the effects of the initial quinoline and 1-benzothiophene concentrations, mass solvent ratio, extraction stages, and the presence of other aromatics on the extraction efficiency. Then, the extraction mechanism and the differences in the extraction effects for the quinoline and 1-benzothiophene systems were explored by quantum chemical calculation and molecular dynamics simulation. The consistency between experiments and theoretical calculation indicates that the electrostatic interaction is the main reason for the difference in the extraction efficiency between the quinoline and 1-benzothiophene systems.

Experimental and Mechanistic Analysis of Chlorinated Volatile Organic Compound Capture by Quaternary Ammonium-Based Deep Eutectic Solvents

“…The effectiveness of the absorbent is crucial in the absorption process. Researchers are currently focused on ionic liquids due to their distinct properties. − Ionic liquids are regarded as optimal solvents because of their nonvolatile nature, flexibility in design, and other features. − For instance, Zhao and colleagues designed and conducted an experiment to separate C 2 H 2 /C 2 H 4 using an ionic liquid and the COSMO-RS model . Meanwhile, Yang and colleagues conducted a comprehensive study on the synthesis, characterization, and application of a long-chain fatty acid phosphorus ionic liquid with strong hydrogen bond basicity and good lipophilicity for extraction purposes .…”