Investigation of Ni-B Alloys for Joining of TiB2 Ultra-High-Temperature Ceramic

Xi, L.; Kaban, I.; Nowak, R.; Bruzda, Grzegorz; Sobczak, N.; Stoica, M.; Eckert, J.

doi:10.1007/s11665-016-1958-y

Cited by 10 publications

(7 citation statements)

References 32 publications

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“…SEM analysis of the cross‐sectioned solidified sample (Figure A) revealed that the apparent decrease in the contact angle is due to a dissolution of the substrate in the drop . A large crater (depth up to about 230 μm) at the Ni/TiB 2 interface is similar to those formed by Ni/HfB 2 and Ni 83 B 17 /TiB 2 liquid/ceramic interactions. The behavior of liquid Ni on TiB 2 at 1500°C correlates with the wetting test carried out at 1450°C by Samsonov et al .…”

Section: Resultsmentioning

confidence: 69%

“…Investigations of high‐temperature wettability and interfacial interactions between liquid metals and ceramics are driven, for example, by the technological demand in obtaining advanced in situ composites, additive manufacturing, and reliable joining of ultrahigh‐temperature ceramics for aggressively chemical and/or thermal environments . In this view, the Ni–Al/TiB 2 system is particularly interesting .…”

Section: Introductionmentioning

confidence: 99%

“…Investigations of high-temperature wettability and interfacial interactions between liquid metals and ceramics are driven, for example, by the technological demand in obtaining advanced in situ composites, additive manufacturing, and reliable joining of ultrahigh-temperature ceramics for aggressively chemical and/or thermal environments. [1][2][3][4][5][6][7][8][9][10][11][12] In this view, the Ni-Al/TiB 2 system is particularly interesting. [13][14][15][16][17][18][19][20][21][22][23][24][25] The Ni 3 Al intermetallic is characterized by very good properties at elevated temperatures, such as high tensile and compressive yield strength, fatigue resistance, and oxidation resistance, but it is brittle at room temperature.…”

Section: Introductionmentioning

confidence: 99%

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Wetting, reactivity, and phase formation at interfaces between Ni–Al melts and TiB₂ ultrahigh‐temperature ceramic

Kaban

Nowak³

et al. 2017

J Am Ceram Soc

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The wetting, reactivity, and phase formation at the liquid Ni–Al/TiB2 ceramic interfaces have been investigated at the temperatures close to the Ni–Al liquidus line. The wetting kinetics has been studied by the sessile drop technique utilizing liquid drop dispension and high‐speed high‐resolution video imaging. It is established that the wetting behavior changes from a nonreactive for the Al‐rich melts to a dissolution‐reactive for the Ni‐rich melts. For the Ni concentration ≥40 at.%, TiB2 precipitates are found in the solidified Ni–Al droplets after the high‐temperature interaction of the melts with TiB2 substrates. Besides, new (Al,Ti)Ni3 and (Al,Ti)2Ni21B6 phases are formed due to dissolution of TiB2 ceramic in Ni‐rich melts and subsequent solidification.

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Section: Resultsmentioning

confidence: 69%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Wetting, reactivity, and phase formation at interfaces between Ni–Al melts and TiB₂ ultrahigh‐temperature ceramic

Kaban

Nowak³

et al. 2017

J Am Ceram Soc

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“…These means that the formation of the TiB 2 phase was more stable than the nickel borides and therefore, the largest amount of boron in the mixture reacted with titanium, resulting in a minimum relation of B/Ni in equilibrium; but enough to the formation of Ni 2 B phase [12,13]. …”

Section: Mechanical Alloyingmentioning

confidence: 99%

Synthesis of TiB2-Ni3B Nanocomposite Powders by Mechanical Alloying

Hernández¹,

Escobedo²,

Hernández³

et al. 2018

Novel Nanomaterials - Synthesis and Applications

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Combination of good oxidation resistance, thermal stability, hardness and high strength are great interest properties in engineering and, that are possible to obtain with the Ni-Ti-B ternary system. Mechanical alloying (MA) is an alternative method and cheapest for the synthesis of this kind of metal-ceramic materials with respect to the traditional melt and quench process. The transformation sequence of all the mixtures reported the formation of (ɣ Ni) phase with a nodular morphology and identified the additional presence of the TiB 2 phase (needle morphology), which was more evident with the increase of titanium content (M2 and M3 mixtures) after 24 h of milling. Thermal activation of the milled powders showed the nucleation and growth of the Ni 3 B (O boride) and TiB 2 (Hex) as the main phases after heat treatment, where the TiB 2 phase (thin flakes morphology) was nucleated onto Ni 3 B matrix. Ternary alloy by MA took place under a metastable equilibrium, offering the possibility to form glassy alloys for compositions, which are not accessible by melting or quenching techniques.

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“…The high melting temperature, thermal conductivity, elastic-plastic behavior, resistance to erosion, and corrosion make metal-ceramic materials suitable for high-performance applications [2].…”

Section: Introduction 1the Importance Of Metal-ceramic Materialsmentioning

confidence: 99%

Synthesis of TiB₂-Ni₃B nanocomposite coating by DC magnetron sputtering for corrosion-erosion protection

Hernández¹,

Juarez

Basurto

et al. 2021

Mater. Res. Express

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Significant contribution on corrosion-erosion resistance of Ni3B-TiB2 nanocomposite coating of 1µm of thickness, deposited by DC magnetron Sputtering on stainless steel 304 substrates was studied. Nickel phase (γ Ni) plus Ni3B-TiB2 phases were synthesized previously by Mechanical Alloying (MA). Solid cathode (76.2 mm of diameter and 3 mm of thickness) used to grow thin films was manufactured with the alloyed powders, applying a uniaxial load of 70 MPa at room temperature and sintered at 900° C for two hours. Microstructure and mechanical properties of the coatings were characterized by X-Ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), nanoindentation, and wear test with a ball-on-disc tribometer. Compact coating of Ni3B-TiB2 with a microstructure of prismatic crystals after annealing treatment, showing a uniform coating with good adherence and low friction coefficient of 0.5, correlated with a low roughness of Ra ≈ 0.0439±0.0069 µm. The average hardness of 537.4 HV (5265.0 MPa) and wear coefficient at room temperature of 2.552E-10 m2N-1 correspond with medium-hard phases with an elastic-plastic behavior suitable for fatigue applications. Geothermal fluid modified was synthesized in the lab with NaCl/Na2SO4 to evaluate the corrosion resistance of the films in a standard three electrodes cell, characterizing a corrosion rate of 0.0008 and 0.001 mm*year-1 at 25 and 80°C respectively during 86.4 ks (24 h) of exposition; showing a resistive coating without corrosion products and with good response to the geothermal environment.

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Investigation of Ni-B Alloys for Joining of TiB2 Ultra-High-Temperature Ceramic

Cited by 10 publications

References 32 publications

Wetting, reactivity, and phase formation at interfaces between Ni–Al melts and TiB₂ ultrahigh‐temperature ceramic

Wetting, reactivity, and phase formation at interfaces between Ni–Al melts and TiB₂ ultrahigh‐temperature ceramic

Synthesis of TiB2-Ni3B Nanocomposite Powders by Mechanical Alloying

Synthesis of TiB₂-Ni₃B nanocomposite coating by DC magnetron sputtering for corrosion-erosion protection

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Investigation of Ni-B Alloys for Joining of TiB2 Ultra-High-Temperature Ceramic

Cited by 10 publications

References 32 publications

Wetting, reactivity, and phase formation at interfaces between Ni–Al melts and TiB2 ultrahigh‐temperature ceramic

Wetting, reactivity, and phase formation at interfaces between Ni–Al melts and TiB2 ultrahigh‐temperature ceramic

Synthesis of TiB2-Ni3B Nanocomposite Powders by Mechanical Alloying

Synthesis of TiB2-Ni3B nanocomposite coating by DC magnetron sputtering for corrosion-erosion protection

Contact Info

Product

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Wetting, reactivity, and phase formation at interfaces between Ni–Al melts and TiB₂ ultrahigh‐temperature ceramic

Wetting, reactivity, and phase formation at interfaces between Ni–Al melts and TiB₂ ultrahigh‐temperature ceramic

Synthesis of TiB₂-Ni₃B nanocomposite coating by DC magnetron sputtering for corrosion-erosion protection