The
Lower Cambrian shale is one of the most important marine shale
reservoirs in South China, which has huge potential for shale gas
resources. However, the Lower Cambrian shale displays strong pore
heterogeneity, influencing shale gas exploration. Based on the low-pressure
N2 adsorption (LPNA) of the Lower Cambrian shale samples
and their isolated kerogens in the western Hubei area, South China,
fractal dimensions and their controlling factors of shale nanopores
have been investigated. In this study, the pore specific surface area
(SSA) and pore volume (PV) of isolated kerogen samples are mainly
contributed from micropores and non-micropores, respectively, which
are consistent with those of whole-rock samples. The average fractal
dimensions of whole-rock samples are higher than those of isolated
kerogen samples, suggesting that organic matter (OM) controls the
shale pore structure and exerts major influences on fractal characteristics
of nanopores and inorganic mineral (IM) enhances the complexity of
shale nanopores. The correlations between fractal dimensions and total
organic carbon (TOC) and IM contents of whole-rock samples further
indicate that the OM simultaneously affects the heterogeneities of
the pore surface and structure, while the IM mainly affects the heterogeneity
of the pore structure. They both control the fractal characteristics
of nanopores in the Lower Cambrian shale. Compared with the Upper
Carboniferous–Lower Permian marine-continental transitional
(MCT) shale and the Lower Silurian marine shale, the D
1 and D
2 of the studied marine
shale display relatively lower and higher values, respectively, revealing
that the Lower Cambrian shale has relatively weak adsorption capacity,
as well as poor permeability and connectivity.