“…The PM samples had significant peaks at about 730, 1100, 1450, 1720, and 2900 cm −1 , which were caused by the bending vibration of the unsaturated hydrocarbon group ═C-H, the C-O stretching vibration of the hydroxyl group, the asymmetric deformation vibration of the C-H of the saturated hydrocarbon group, and the C═O and C-H stretching vibration of the carbonyl group, respectively. [32,33] As shown in Figure 8, the PM produced by the engine under all test loads contained many alkanes, alkenes, alcohols, and aldehydes, and the content of various functional groups changed with the engine load. When the engine load was 25%, the strength of the C-O and C═C bonds in the NTP-treated samples was relatively low and the strength of the C═O bond was relatively high, indicating that the NTP active gas had converted part of the C-O and C═C to C═O.…”