The pyrolysis mechanism of Phenolic Impregnated Carbon Ablator (PICA) makes it a viable candidate for thermal protection systems for spacecraft atmospheric entry. However, a better understanding of the pyrolysis mechanism and of the interaction of the pyrolysis gases with the plasma flow is needed to improve heat-shield designs. The present study extends previous work in the design, development, and testing of a gas-injection probe to simulate pyrolysis in the UVM 30kW Inductively Coupled Plasma (ICP) Torch Facility. A parallel effort in Computational Fluid Dynamics (CFD) modeling of the injection probe during plasma testing is also discussed. Measurements were obtained with the injection probe in the facility in an argon buffered nitrogen condition with carbon dioxide being injected into the flow through a FiberForm plug. Spatially resolved high-resolution emission data were acquired during this test. Spectral signatures of CN, OH, and NH bands were detected and their spatial locations determined using a spectrometer equipped with a CCD camera at the exit plane. At the same time the relative conditions in the facility were used to create a CFD model of the experiment. Comparisons between the measured, spatially resolved, emission spectra and the simulations calculated using a radiative transport model from the CFD results show reasonable agreement.