In this investigation, the mixed γ-GPS/BTSE silane solution for preparing well adhered composite γ-GPS/BTSE silane film on Q235 carbon steel surface has been successfully optimized by orthogonal test, and the curing process parameters of temperature and time have also been optimized. The results indicate that the optimized hydrolysis parameters for mixed silanes agent solution are as follows:silanes 6 vol.%, pH 4.0 and hydrolysis time 72 h. In addition, the optimized curing condition for composite γ-GPS/BTSE silane film is 120°C and 30 min. After immersion in the optimized mixed γ-GPS/BTSE silanes agent solution and curing under the optimized condition, the prepared composite γ-GPS/BTSE silane film on Q235 steel surface can have an adhesion strength of 24.52 MPa to underlying steel substrate. Keywords: Epoxy resin / silane treatment / orthogonal test / adhesion / Q235 steel Schlüsselwörter: Epoxidharz / Silanbehandlung / orthogonaler Test / Haftung / Adhäsion / Q235 StahlFigure 4. Effect of composite silane film curing temperature on the adhesion of epoxy resin coating to Q235 steel substrate.Figure 5. Effect of composite silane film curing time on the adhesion of epoxy resin coating to Q235 steel substrate.Composite γ-GPS/BTSE silane film on Q235 steel surface Materialwiss. Werkstofftech. 2020, 51, 480-487