“…From Table and Figure , we can observe that all the values of ϕ v 0 are positive, which further increase with increasing temperature as well as the molality. ϕ v 0 is sensitive to solute–solvent interaction in an aqueous medium and provides information regarding the structural volume of solute in solvent media and volume change of solvent during the shell formation surrounding the ions . It is found that ϕ v 0 values are higher for the l -leucine system compared with the l -valine system, indicating that more hydration of ions in the case of l -leucine undergoes greater interactions.…”