Two-dimensional
(2D) Sn-based lead-free perovskites have attracted
extensive attention because of their nontoxicity and wide light absorption.
It has been proven that the introduced organic spacer cations in the
perovskite crystal prevent Sn2+ from oxidation to Sn4+. However, the effects of the alkyl chain length of these
cations on the perovskite properties are unclear. Here, we investigate
the impacts of chain length on crystal orientation and phase distribution
of 2D Sn-based perovskite films by employing different alkylamines
spacer cations (butylamine, octylamine, and dodecylamine). With the
increase of alkyl chain length, the phase distribution of 2D Sn-based
perovskite crystals become disordered and less oriented. Therefore,
benefiting from application of a short alkyl chain in the organic
spacer cation (e.g., BA), we manage to retard the oxidation process
of Sn2+ for better device performance. Our work provides
systematic understanding of configuration and size of organic spacer
cations, which will further contribute to highly stable and efficient
lead-free perovskite solar cells.