Investigation of the copolymerization of peroxide monomers with a buta-1,3-diene-styrene mixture and a study of their polymers

Yurzhenko, T. I.; Chuiko, L.S.; Kirichek, Alex; Karpenko, A. N.; Mamchur, L. P.

doi:10.1016/0032-3950(71)90381-9

Cited by 5 publications

(2 citation statements)

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“…The presence of the groups which are able to generate radicals and at the same time interact with the radicals determines the PM-specific behavior in polymerization reactions. The radical copolymerization of PMs has been widely studied. ,,,− Peroxide monomers can be copolymerized with vinyl and diene monomers without any additional radical initiators because of the peroxide group’s decomposition. ,− …”

Section: Introductionmentioning

confidence: 99%

“…1,6,7,[11][12][13] Peroxide monomers can be copolymerized with vinyl and diene monomers without any additional radical initiators because of the peroxide group's decomposition. 1,[6][7][8][9][10][11][12][13] The new class of reactive polymers, called functional polyperoxides (FPPs), is based on the PMs. They have been recently designed and employed for synthesis and modification of polymer composites.…”

Section: Introductionmentioning

confidence: 99%

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A New Acrylamide-Based Peroxide Monomer: Synthesis and Copolymerization with Octyl Methacrylate

et al. 2009

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N-[(tert-Butylperoxy)methyl]acrylamide (tBPMAAm), a new peroxide monomer containing a primary-tertiary peroxide group, was synthesized and employed for radical copolymerization with octyl methacrylate (OMA) to yield a novel functional polyperoxide (FPP). Copolymerization kinetics were analyzed to find tBPMAAm and OMA monomer reactivity ratios (r 1 , r 2 ) and Qe values. Kinetic characteristics provide a way to control FPP composition and its reactivity in radical processes. It is expected that the developed functional polyperoxide containing long alkyl fragments provides an affinity to polymeric surface. At the same time, since the peroxide groups readily decompose at elevated temperatures, the FPP can be used as a macroinitiator of radical polymerization. As a result, we expect that in the future the FPP will be applied as an efficient modifier of the polymeric surface.

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