Investigation of the corrosion resistance of graphene-nickel composite micro-parts

Abstract

Nickel-based microparts possess a short lifetime owing to their rapid dissolution in corrosive environments. To mitigate this phenomenon, composite microparts of graphene/Ni were prepared using UV-LIGA technology; their corrosion behavior was examined in acid, alkali, and salt solutions as well as after subjecting them to heat-treatment processes. The microstructures were investigated with scanning electron microscopy (SEM), X-ray diffraction (XRD), electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). Corrosion resistances were characterized through various electrochemical tests and compared with those of pure Ni microparts. The results demonstrate that the surface oxidation layer (i.e.,the protective layer) of the microparts was readily destroyed in NaCl and H2SO4 solutions without the formation of a passivation film; however, a passivation film was formed in the NaOH solution. The corrosion rates of graphene/Ni in NaCl, NaOH, and H2SO4 corrosion solutions were reduced by 73%, 22%, and 84%, respectively, relative to those of pure Ni microparts. This can be primarily attributed to the homogeneous dispersion of graphene in the Ni matrix, which refined the grain size, and the impermeability and chemical stability of graphene, which lengthened the diffusion path of the corrosive medium. In addition, heat treatment of the graphene/Ni microparts at 200 °C increased the corrosion resistance by a factor of nearly one with little change in microhardness, which can be attributed to the removal of internal stress and the increased proportion of CSL grain boundares. Corrosion occurred at the interface between nickel and graphene, lengthening the corrosion path.