The interfacial properties
of a heterogeneous composite flooding
system containing a surfactant fatty alcohol polyoxyethylene carboxylate
(C
12
EO
3
C), branched-preformed particle gel (B-PPG),
and polymer partly hydrolyzed polyacrylamide (HPAM) at the crude oil–water
interface were investigated by a dilational rheology method. The results
demonstrated that the C
12
EO
3
C molecules can
form an elastic interfacial film with certain strength at the crude
oil–water interface. The addition of HPAM to the C
12
EO
3
C solution has a detrimental effect on the interfacial
film formed by C
12
EO
3
C molecules, leading to
a decrease in the dilational modulus and an increase in the phase
angle. Moreover, the addition of B-PPG to the C
12
EO
3
C solution also disrupts the stability and strength of the
interfacial film of C
12
EO
3
C. In particular,
linear HPAM with a lower steric hindrance is more likely to insert
into the interfacial film of C
12
EO
3
C; thus,
HPAM possesses a stronger destruction ability for the interfacial
film of C
12
EO
3
C than B-PPG. When HPAM is compounded
with B-PPG, a superimposed effect exists to cause more severe disruption
for the interfacial film. The heterogeneous composite flooding system
not only enhances oil recovery by increasing the viscosity of the
bulk phase but also weakens the interfacial film to facilitate the
post-treatment of the recovered crude oil. Thus, the heterogeneous
composite flooding system exhibits promising prospects in practical
application.