Investigation of the structure, pyro- and piezoelectric properties of a ferroelectric ceramic of PZT+(fesb)

Dielectric and Pyroelectric Properties of Pb[(Fe1/3Sb2/3)xTiyZrz]O3Ceramics

“…1). According to the structural data presented in [27] the change of the volume of pseudoperovskite cell is observed near 520 K. At room temperature the symmetry of the PFS-PZ-yPT samples was found to be rhombohedral. This symmetry gradually changes with temperature to the tetragonal one and the observed anomalies can be connected to the change of the volume content of the rhombohedral and tetragonal phase.…”

“…The existence of ferrroelectrics phases below 530 K < T m was confirmed. According to the X-ray measurements made by Osak et al [27] the symmetries of the ferroelectric phases are rhombohedral and tetragonal respectively. two ferrroelectric phases suggests that PFS-PZ-yPT solutions can be attractive materials for pyroelectric devices.…”

“…The results of X-ray diffraction studies were performed by Osak et al [27]. From these investigations it follows that the rhombohedral and tetragonal phases coexist below 500 K. Phase composition of the samples depends on the temperature and the amount of rhombohedral phase decreases with increasing temperature.…”

Phase transitions in Pb[(Ni1/3Sb2/3)xTiyZrz]O3 solid solution ceramics studied by piezoelectric measurements

“…Recently it has been found that solid PZT solutions with complex perovskite relaxors such as PMN, PZN, PNN and PFS [18][19][20][21][22][23][24][25][26] exhibit excellent both electromechanical and pyroelectric properties.…”

AC low frequency conductivity in PZT PFS ferroelectric ceramics

“…In the studied complex compound PZT + PFS (Pb[(Fe 1/3 Sb 2/3 ) x Ti y Zr z ]O 3 with x + y + z = 1, x = 0.1 and y = 0.43, 0.44, 0.47) the crystal lattice Pb sites are partially replaced by Sb cations while the Ti sites by Zr or Fe cations. The structural studies performed for the 0.43 and 0.44 of Ti content samples established the existence of the MPB region [5]. The coexistence of rhomboedral and tetragonal phases in the MPB range as well as doping leads to structural disorder in the studied compound.…”