Investigation of titanium-catalysed dehydrogenative coupling and hydrosilylation of phenylhydrogenosilanes in a one-pot process

Elaboration of porous silicon carbide by soft templating molecular precursors with semi-fluorinated alkanes

“…In order to obtain the preceramic polymer, the TSCH is polymerized by catalytic dehydrogenative coupling in a Schlenk ask under argon atmosphere at room temperature using bis(cyclopendienyl)-bis(diphenoxy)titanium (Cp 2 Ti(OPh) 2 ) as catalyst 32,33 which was synthesized using an adapted protocol proposed by Andrä 34 (see ESI †).…”

Elaborating ordered silicon carbide nanorods by preceramic polymer nanocasting

“…In order to obtain the preceramic polymer, TSCH was polymerized at room temperature by a catalytic dehydrogenative coupling in a Schlenk ask under argon atmosphere using bis(cyclopentadienyl)-bis(diphenoxy)titanium as catalyst prefunction. 35,36 This catalyst was synthesized using an adapted protocol proposed by Andrä. 37 The dehydrogenative polymerization of TSCH results in the poly-1,3,5-trisilacyclohexane (pTSCH), which can be obtained with various degrees of polymerization depending on the reaction time.…”

Cobalt-Catalyzed Regiodivergent Hydrosilylation of Vinylarenes and Aliphatic Alkenes: Ligand- and Silane-Dependent Regioselectivities

“…Platinum-catalyzed hydrosilylation of alkenes is one of the most frequently conducted catalytic processes in industry due to its effectiveness and high selectivity . A number of other metals, such as lanthanides, early transition metals, iron, cobalt, nickel, rhodium, and iridium, have also been used for this transformation. The majority of these catalysts show high selectivity toward anti -Markovnikov hydrosilylation.…”