Investigation of Volume Changes in Carbon Dioxide Hydrate Formation Process

Abstract

Gas hydrate formation is a new technology to uptake carbon dioxide. In the present work, the kinetics of changes in the volume of unreacted water, the formed carbon dioxide hydrate, and also the unreacted gas inside the reactor were investigated with the passage of time. Experiments were performed in a stagnant 169 cm 3 double-walled reactor at a temperature of 275.15 K and a pressure of 3 MPa. The tests were done by using the isochoric-isothermal method. The results of the experiments showed that the volume of unreacted water decreased with respect to time and the volume of hydrate formed increased. Taking into account the different molar volumes of hydrate formed and the molar volume of reacted water in the test conditions, the changes in gas volume inside the reactor were calculated with the passage of time. The gas volume inside the reactor decreased from 144 cm 3 at the beginning of the process to 141.62 cm 3 at the end of the reaction. By decreasing the pressure during carbon dioxide hydrate formation process, the amount of hydration number increased from 6.047 mol/mol to 6.109 mol/mol.

Energy Efficiency of Residential Buildings in Cold and Dry Climates using Simulation-based Comparative Analysis: Case Study in Tabriz

“…INTRODUCTION 1 Buildings are responsible for approximately 40% of the world's total energy consumption and carbon emissions, making this a critical and prevalent issue in today's global context (1). In fact, around 27% of carbon dioxide (CO2) emissions in developing countries can be attributed to buildings, primarily due to heat loss within residential structures (2,3). The significance of the built environment extends beyond energy consumption during construction and occupancy (4).…”