In hemisphere point temperature (Thp) measurement of continuous casting mold
flux, the evaporation of volatiles under high temperature will have a strong
impact on the results. Based on the comprehensive analysis of hemisphere
point method and its influencing factors, the corresponding
volatile-containing mold flux and non-volatile mold flux were selected to
get Thp with different heating rates. Combined with the Thp measurement and
TG-DSC results, the effect of relevant factors during measuring process were
analysed and the way to characterize and evaluate the effects were
suggested. Furthermore, an improved method of mold flux melting point test
was put forward. The results showed that for non-volatile mold flux, the
temperature hysteresis has a greater effect than heat transfer delay and
fractional melting. And for mold flux with volatile, the effect of
evaporation is greater than other factors. Traditional hemisphere-point
method is no longer suitable for the volatile mold flux. In order to get
through this problem, improved methods were proposed. One is measuring Thp
by traditional way, correcting the composition at the Thp, corresponding Thp
with the corrected composition. Another is taking the initial composition,
revising the hemispherical point temperature Thp, matching the revised Thp
with the initial composition.