High-temperature syngas is produced by entrained-flow coal gasification. A traditional quenching process has the drawback of low heat recovery efficiency, and the cleaning of convective syngas cooler is a big problem. Thus, the combination of a radiant syngas cooler and a quench chamber is a more promising way for heat recovery and syngas preliminary purification. In this study, based on the traditional radiant syngas cooler, sixteen radiation screens are added to increase the heat exchange area, so as to further improve heat recovery efficiency of the radiant syngas cooler. Heat transfer and structure analysis of a forging plate on the top of the radiation screen are carried out by numerical simulation. The radiation screen changes the internal spatial structure of the radiant syngas cooler, which also affects the heat transfer characteristics of the membrane wall. The circumferential temperature distribution of the cylinder membrane wall is not uniform, and the temperature is the highest at the central pipe. The surface heat flux of the cooling pipes on the radiation screen reaches the maximum value at the position with a distance of about 6 m from the top. The slag and fly ash carried in the gas flow deposit on the wall surface and form deposition layers, which protects the forging plate and cooling pipes, but reduces the heat transfer efficiency.