Their experimental observations confirmed the Bo-Md approach could be useful in terms of designing new Ti-rich BCC-HEAs. It should be noted however, the relevance and validity of these predictions based on this controlled alloy strategy for other alloys is not yet fully explored. The primary objective of the present study is to investigate deformation mechanisms of new Ti-rich BCC-HEAs designed using the Bo-Md approach. Given the vast compositional space of HEAs, appropriate alloying elements must be chosen in order to exploit the required properties in terms of designing new HEAs. Here, we designed two new Ti-rich HEAs having chemical compositions Ti 38 Zr 25 Hf 25 Ta 7 Sn 5 , Ti 38 Zr 25 Hf 25 Ta 10 Sn 2 to compare them with the Ti 35 Zr 27.5 Hf 27.5 Nb 5 Ta 5 alloy. It is known that an addition of Sn increases β stability of Ti-alloys 14-16. Furthermore, the combination of Ta and Sn alloying elements were previously reported to have advantages in terms of tuning the martensite formation temperature 15. Therefore, in the present study, first we chose the Ti 35 Zr 27.5 Hf 27.5 Nb 5 Ta 5 alloy 13 as a base reference and replaced Nb with Sn, and adjusted the overall chemical compositions as Ti 38 Zr 25 Hf 25 Ta 10 Sn 2 , and Ti 38 Zr 25 Hf 25 Ta 7 Sn 5 to make sure the alloys positions are maintained along or near the M s ~ RT domain, on the Bo-Md diagram. Latter, the obtained alloys were characterized and their deformation mechanisms were systematically investigated.