Combustion and explosion
accidents of the mixture may
occur after
the adsorption of volatile organic compounds (VOCs) by coal-based
activated carbon (CBAC). It is of great significance to explore the
oxidation and combustion performance of CBAC before and after adsorbing
VOCs in order to prevent the reoccurrence of fire and explosion. Based
on the CBAC sample commonly used in industrial production, three types
of CBAC samples after adsorbing VOCs, i.e., acetone, cyclohexane,
and butyl acetate, were prepared. The oxidation and combustion characteristics
of the samples before and after adsorbing VOCs are measured and analyzed
by thermal analyzer and cone calorimeter. Thermal analysis results
indicate that during the oxidation process, the VOCs in the adsorbed
samples will burn in the early stage, generating amounts of heat which
may accelerate the oxidation and combustion of CBAC. According to
the combustion performance experiments by cone calorimeter, it is
also found that the combustion rate of CBAC after adsorbing VOCs is
significantly enhanced. The time to ignition is shortened, the heat
release rate becomes larger, and the time to reach the peak of heat
release rate is significantly moved forward. In addition, the CO yield
of the adsorbed sample is significantly improved. In general, VOC
adsorption in CBAC can promote oxidation reactions and may result
in an enhanced combustibility of CBAC.