Investigations on Na+ ion conducting polyvinylidenefluoride-co-hexafluoropropylene/poly ethylmethacrylate blend polymer electrolytes

Aravindan, Vanchiappan; Lakshmi, C. Vijaya; Vickraman, P.

doi:10.1016/j.cap.2008.12.009

Cited by 35 publications

(20 citation statements)

References 15 publications

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“…Based on Debye-Scherrer equation, the broader the diffraction peak width, the shorter the crystallite size is. Hence, it contributes to lower crystallinity and higher ionic conductivity [25]. As proven in Fig.…”

Section: X-ray Diffraction (Xrd) Studiesmentioning

confidence: 97%

Evaluation and investigation on the effect of ionic liquid onto PMMA-PVC gel polymer blend electrolytes

Ramesh

Liew

2011

Journal of Non-Crystalline Solids

143

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Section: X-ray Diffraction (Xrd) Studiesmentioning

confidence: 97%

Evaluation and investigation on the effect of ionic liquid onto PMMA-PVC gel polymer blend electrolytes

Ramesh

Liew

2011

Journal of Non-Crystalline Solids

143

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“…The addition of very high SN content results in the insulating effect of SN due to improper mixing as visible in Figure 1d [23]. …”

Section: Field Emission Scanning Electron Microscope (Fesem) Analysismentioning

confidence: 97%

Tailoring the Structural, Morphological, Electrochemical, and Dielectric Properties of Solid Polymer Electrolyte

Arya¹

2018

Preprint

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Abstract:Herein, we present preparation of solid polymer electrolyte (SPE) comprising of PEO, NaPF6 and varying fraction of Succinonitrile (SN) by standard solution cast technique. The morphological features and structural properties were studied by the FESEM, XRD, respectively. FTIR was performed to study the interactions between polymer host, salt, and SN. Impedance spectroscopy, Transference number measurements, LSV and CV were used to examine the electrochemical properties. The complex permittivity/conductivity & modulus were studied to understand the dielectric properties by evaluating the dielectric strength, relaxation time, hopping frequency and dc conductivity. Based on the experimental results an interaction mechanism is presented.

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“…It's widely used because of its great interest in many industrial applications and various fields, such as enhancing of electrical properties of schottky diode and conductivity of batteries 2,3 . Also, polymers systems, containing PEMA, shown use in dental applications, drug release and cartilage repair [4][5][6][7] .…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of New Copolymer Based Cinnamyl Methacrylate Monomer: Determination of Monomer Reactivity Ratio and Statistical Sequence

Lerari

2015

Mat. Res.

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Radical-initiated copolymerization of Cinnamyl methacrylate (CMA) and Ethyl methacrylate (EMA) monomers were carried out at lower conversions (<10%) using 2,2'-azobisisobutyronitrile (AIBN) as initiator, in 1,4-dioxane at 60 °C and nitrogen atmosphere. Structure and composition of copolymers for wide range of monomer feed were determined by Fourier Transform Infrared (FTIR) and Ultra-violet (UV) spectroscopy analysis through recorded of analytical absorption bands for monomers units. Monomer reactivity for CMA (1)-EMA (2) pair were determined by the Finneman-Ross (F-R) and Kelen-Tudos (K-T) methods. They are r 1 = 0.135 and r 2 = 0.868 as determined by K-T method. Parameters Q 1 , e 1 of CMA monomer were calculated according to Alfrey-Price model. A relatively high activity of EMA was observed as compared to CMA growing radical. This result can be explained by sterical hindrance caused by chemical structure of cinnamyl pendant group in chain growth reactions.

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Investigations on Na+ ion conducting polyvinylidenefluoride-co-hexafluoropropylene/poly ethylmethacrylate blend polymer electrolytes

Cited by 35 publications

References 15 publications

Evaluation and investigation on the effect of ionic liquid onto PMMA-PVC gel polymer blend electrolytes

Evaluation and investigation on the effect of ionic liquid onto PMMA-PVC gel polymer blend electrolytes

Tailoring the Structural, Morphological, Electrochemical, and Dielectric Properties of Solid Polymer Electrolyte

Synthesis and Characterization of New Copolymer Based Cinnamyl Methacrylate Monomer: Determination of Monomer Reactivity Ratio and Statistical Sequence

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