Iodosylbenzene

Moriarty, Robert M.; Kosmeder, Jerome W.; Zhdankin, Viktor V.; Courillon, Christine; Lacôte, Emmanuel; Malacrìa, Max

doi:10.1002/047084289x.ri039.pub3

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Mn Catalysis2

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2023

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“…The utility of the method on scale may be limited by use of iodosobenzene, which is generally poorly soluble and has some potential stability issues. 48 The Cho group speculated that the oxonium intermediate in the reaction may be trappable with other nucleophiles to enable formation of different functional groups.…”

Section: Mn Catalysismentioning

confidence: 99%

“…Mechanistic studies revealed the reaction to proceed via a net hydride transfer from the aldehyde to the catalyst, forming an intermediate oxonium species which reacts further to form the carboxylic acid. The utility of the method on scale may be limited by use of iodosobenzene, which is generally poorly soluble and has some potential stability issues . The Cho group speculated that the oxonium intermediate in the reaction may be trappable with other nucleophiles to enable formation of different functional groups.…”

Section: Mn Catalysismentioning

confidence: 99%

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