Ion-imprinted poly(2-acrylamido-2-methyl-1-propansulfonic acid)/modified silica composite hydrogel for selective and enhanced adsorption of Pb(II) ions

Abstract

To cite this article: Jingjing Wang & Xianning Li (2014) Ion-imprinted poly(2-acrylamido-2-methyl-1-propansulfonic acid)/ modified silica composite hydrogel for selective and enhanced adsorption of Pb(II) ions, Desalination and Water Treatment, 52:1-3, 274-282, A B S T R A C TIn this research, ion-imprinted poly(2-acrylamido-2-methyl-1-propansulfonic acid)/modified silica composite hydrogels were prepared using Pb(II) ions as template by in situ free-radical polymerization. The ability of the imprinted composite hydrogels to adsorb and remove Pb (II) ions from aqueous solutions was assessed using batch adsorption technique. The adsorption amount was pH-dependent, and the maximum adsorption capacity was observed at pH 5.0. The adsorption process could be well described by the Langmuir isotherm. The adsorption equilibrium was achieved within 15 min, and the kinetics of adsorption followed a pseudo-second-order rate equation. Thermodynamic parameters such as the Gibbs free energy (DG 0 ), enthalpy (DH 0 ), and entropy (DS 0 ) for the metal ion adsorption were estimated. Results suggested that the adsorption process was a spontaneous, exothermic process that had positive entropy. The Pb(II) ion-imprinted composite hydrogels exhibited extremely high selectivity coefficient, which was much higher than that of corresponding non-imprinted composite hydrogels. Regeneration studies suggested that metal ion rebinding capacity of the Pb(II) ion-imprinted composite hydrogels did not change significantly through six cycles of sorption-desorption process.

Synthesis and application of a surface-grafted In (III) ion-imprinted polymer for selective separation and pre-concentration of indium (III) ion from aqueous solution

“…The maximum adsorption capacities of In (III)-IIP and In (III)-NIP were calculated to be 43.87 and 26.53 mg·g −1 , respectively. It may be due to the fact that the cavities created after the removal of the metal ion were matched with the imprint ion in size and coordination geometries, whereas in In (III)-NIP there was a random distribution (Wang and Li, 2014).…”