1951
DOI: 10.1002/zaac.19512640209
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Ionenreaktionen in geschmolzenem Jodmonochlorid

Abstract: Jodmonochlorid verhält sich als ionisierendes, nichtwässeriges Lösungsmittel. Seine Eigenleitfähigkeit beruht auf Eigendissoziation: 2 JCl ⇄ J+ + JCl −2. Die Chloride des Kaliums, Ammoniums, Rubidiums und Caesiums sind leicht löslich und bilden die in Lösung stark dissoziierten Di‐Chlorjodide, die in geschmolzenem Jodmonochlorid basenanaloge Stoffe darstellen. Titantetrachlorid, Zinntetrachlorid, Vanadintetrachlorid. Antimonpentachlorid und Niobpentachlorid sind Säureanaloge. Die Verbindung JPCl6 verhält sich … Show more

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Cited by 28 publications
(2 citation statements)
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“…I11 addition to containing different halogens, the pentahalides also form ionic complexes containing two different Group V elements. Thus PCU and SbCI6 react directly on heating (35) and form PC14+ SbCln- (36). Such reactions yield information on the relative stability of ion species.…”
Section: Mixed Pentahalidesmentioning
confidence: 99%
“…I11 addition to containing different halogens, the pentahalides also form ionic complexes containing two different Group V elements. Thus PCU and SbCI6 react directly on heating (35) and form PC14+ SbCln- (36). Such reactions yield information on the relative stability of ion species.…”
Section: Mixed Pentahalidesmentioning
confidence: 99%
“…Spandau and Brunneck (504) found that (C2Hs)4NCl potentiometrically titrated against SbCls in thionyl chloride only gave evidence for a 1:1 complex, but pyridine (and some other nitrogen bases) gave inflections at Py/SbCls mole ratios of 1:1, 2:1, 3:1 ?, and 4:1. Such titration experiments have been carried out in POCl3 (22,189,190,192,194,207, 210, 211); S02C12 (193); SOCl2 (192,504); AsCl3 (9,187,188,191,192); IC1 (183,186,188); S02 (253); BrF3 (557); C6H6C0C1 (213); CeHsPOCl, (30, 31); CHgCC^Hs (421).…”
Section: Conductivity and Potentiometrymentioning
confidence: 99%