Ionic and Organometallic‐Catalyzed Organosilane Reductions

doi:10.1002/9780470572689.ch1

Ionic and Organometallic‐Catalyzed Organosilane Reductions 2009

DOI: 10.1002/9780470572689.ch1

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Ionic and Organometallic‐Catalyzed Organosilane Reductions

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Cited by 2 publications

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Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H₃PO₃/I₂

Xiao

Xiang

et al. 2021

J. Org. Chem.

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For the first time, H 3 PO 3 was used as both the reducing reagent and the promotor in the reductive benzylation reactions with aryl aldehydes. By using a H 3 PO 3 /I 2 combination, various aromatic aldehydes underwent iodination reactions and Friedel−Crafts type reactions with arenes via benzyl iodide intermediates, readily producing benzyl iodides and diarylmethanes in good yields. Intramolecular cyclization reactions also took place, giving the corresponding cyclic compounds. This new strategy features easy-handling, low-cost, and metal-free conditions.

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Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H₃PO₃/I₂

Xiao

Xiang

et al. 2021

J. Org. Chem.

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A Unified Synthetic Approach to the Pleurotin Natural Products

Gao,

Xia,

Zhu

et al. 2024

J. Am. Chem. Soc.

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The asymmetric total syntheses of four pleurotin natural products, namely, (−)-pleurotin, (+)-leucopleurotin, (+)-leucopleurotinic acid, and (+)-dihydropleurotinic acid, were described in a concise manner. Key transformations feature a Johnson−Claisen rearrangement, a diastereo-controlled sequential hydroboration-oxidation, a SOMO/photoredox activated aldehyde α-alkylation, and oxidative cyclizations.

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Ionic and Organometallic‐Catalyzed Organosilane Reductions

Cited by 2 publications

References 971 publications

Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H₃PO₃/I₂

Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H₃PO₃/I₂

A Unified Synthetic Approach to the Pleurotin Natural Products

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Ionic and Organometallic‐Catalyzed Organosilane Reductions

Cited by 2 publications

References 971 publications

Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H3PO3/I2

Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H3PO3/I2

A Unified Synthetic Approach to the Pleurotin Natural Products

Contact Info

Product

Resources

About

Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H₃PO₃/I₂

Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H₃PO₃/I₂