Ionic dissociation in complexes of iodine with triphenylarsine and triphenylstibine

Zhang, Ying Ru; Solomon, Ira; Aronson, S.

doi:10.1139/v91-091

Search citation statements

Order By: Relevance

Paper Sections

Select...

A High Iodine Concentrations1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1992

1995

Publication Types

Select...

Article2

Relationship

Self Cite1

Independent1

Authors

Journals

Cited by 2 publications

(1 citation statement)

References 4 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[4] I2 + TEAI + 1,-+ TEA' R represents the organic molecule. The same assumptions used previously apply here.…”

Section: A High Iodine Concentrationsmentioning

confidence: 99%

Ionic dissociation in complexes of iodine with triphenylphosphine and triphenylamine

Zhang¹,

Aronson²,

Mennitt³

1992

Can. J. Chem.

Self Cite

View full text Add to dashboard Cite

An electrochemical technique has been employed to study the ionization of the iodine complexes of (C6H5)3N and (C6H5)3P. Comparison of the results with a previous study indicates that, at high iodine concentrations, the phosphorus compound behaves like (C6H5)3As and (C6H5)3Sb with the formation of a doubly charged ionic species, (C6H5)3PI22+. The nitrogen compound resembles pyridine in its behavior. Chemical shift data on the (C6H5)3P–I2 system using 31P NMR indicates the presence of additional equilibrium processes.

show abstract

“…[4] I2 + TEAI + 1,-+ TEA' R represents the organic molecule. The same assumptions used previously apply here.…”

Section: A High Iodine Concentrationsmentioning

confidence: 99%