Ionic liquid mediated carbonylation of amines: Selective carbamate synthesis

Recent Advances in Imidazolium-Based Dicationic Ionic Liquids as Organocatalysts: A Mini-Review

“…The same authors also reported the application of these DILs as catalysts in the selective synthesis of carbamates, starting from a diamine and using dimethylcarbonate as a carboxylating agent, without solvent [ 25 ]. The reaction was performed for the carboxylation of an aliphatic (ethylenediamine) and an aromatic ( o -phenylenediamine) amine with dimethyl carbonate ( Scheme 2 ).…”

Current overview and perspectives in environmentally friendly microextractions of carbamates and dithiocarbamates

“…These compounds have been employed since the 1960s in the control and preven-tion of diverse weeds and pests. Their mode of actuation is similar to the organophosphate class that inhibits the acetylcholinesterase enzyme and provides the overstimulation of the nervous system (Ghosh et al, 2015;Verma et al, 2021). However, carbamates toxicity is lower compared to organophosphate, due to its shorter half-life and reversible effects; moreover, their degradation can be accelerated by microbial degradation oxidation and hydrolysis of the compounds (Bhatt et al, 2021;Mishra et al, 2020Mishra et al, , 2021.…”

Ionic liquids as a shuttle for releasing and capturing hydrogen chloride: a new way to utilize waste HCl generated in organic reactions

“…Ionic liquids have been widely employed as solvent and catalyst in organic synthesis and pharmaceuticals chemistry. 18–23 Recently, more attention has been paid to waste as a resource on the basis of the unique properties of ionic liquids. 24–27 Nevertheless, there are few reports on the regeneration and reuse of waste acid in chemical reactions based on ionic liquids.…”