Ionic Liquids in Biotransformations and Organocatalysis 2012
DOI: 10.1002/9781118158753.ch5
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Ionic Liquids as (Co‐)Solvents for Hydrolytic Enzymes

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Cited by 7 publications
(4 citation statements)
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References 394 publications
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“…Correlations of DBT partition coefficient with log P (data from refs , ), and polarity (selected data from refs , ) of ILs.…”
Section: Results and Discussionmentioning
confidence: 99%
“…Correlations of DBT partition coefficient with log P (data from refs , ), and polarity (selected data from refs , ) of ILs.…”
Section: Results and Discussionmentioning
confidence: 99%
“…More importantly, several mechanistic overviews have highlighted some important properties of ILs that influence the enzyme's behaviors in ionic solvents; these properties include IL polarity, hydrogen‐bond (H‐bond) basicity and nucleophilicity of anions, Hofmeister series, IL hydrophobicity, and IL viscosity, etc. However, there is a mixed understanding of the existence of specific ion effect of ILs on protein stabilization and enzyme activation, and how the specific ion effect is different in diluted solutions of ILs from that in concentrated or neat ILs.…”
Section: Introductionmentioning
confidence: 99%
“…The capacitance changes for MMIM [MeSO 4 ] are greater since there is a strong hydrogen interaction between MeSO 4 − and water molecules. 13 The symmetry of the anionic moiety could be another factor that positively impacts the interaction of the RTIL with the water molecules. MMIM [MeSO 4 ] shows greater sensitivity to humidity at lower temperature conditions and their sensitivities are tabulated in Table V.…”
Section: Ecs Journal Of Solid State Science and Technology 7 (7) Q30mentioning
confidence: 99%