2023
DOI: 10.1021/acsami.3c07914
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Ionic Sieving at Sub-Angstrom Precision Enabled by Metal Organic Frameworks

Fengmi Zeng,
Yihui Yang,
Xianhui Li
et al.

Abstract: The demand for cesium is expanding rapidly in light of its necessity in high-tech industries. Thus, technologies that can efficiently extract cesium from the sources are critically needed. Here, the metal−organic framework (MOF) membranes created from −Cl and −NH 2 functionalized MIL-53 enabled highly selective transport of cesium ions. The angstrom-scale pore windows in these MOFs conduct Cs + ions at high throughput, 2 orders of magnitude faster than other marginally larger ions. Ascribed to size sieving eff… Show more

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