2012
DOI: 10.1016/j.fluid.2011.11.002
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Ionic solvation of tetrabutylammonium hexafluorophosphate in pure nitromethane, 1,3-dioxolane and nitrobenzene: A comparative physicochemical study

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Cited by 14 publications
(9 citation statements)
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“…where all the symbols signify their usual meanings. 14 The computations were performed using a program suggested by Fuoss, 19 where initial Λ o (in S m 2 mol −1 ) values for the iteration procedure were obtained from Shedlovsky extrapolation of the data. In a given set, (c j , Λ j , j = 1, ..., n), n, ε r , η (in mPa s −1 ), T (in K), initial Λ o (in S m 2 mol −1 ), and an instruction to cover a preselected range of (R, in Å) values were inputted to run the 1.12922 ± 0.00057 1.12920 13 3.30 3.302 13 109.50 13 a Expanded uncertainties U are U(η) = 0.01 mPa s, U(T)= 0.01 K, and U(p)= 10 kPa (0.95 level of confidence).…”
Section: Resultsmentioning
confidence: 99%
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“…where all the symbols signify their usual meanings. 14 The computations were performed using a program suggested by Fuoss, 19 where initial Λ o (in S m 2 mol −1 ) values for the iteration procedure were obtained from Shedlovsky extrapolation of the data. In a given set, (c j , Λ j , j = 1, ..., n), n, ε r , η (in mPa s −1 ), T (in K), initial Λ o (in S m 2 mol −1 ), and an instruction to cover a preselected range of (R, in Å) values were inputted to run the 1.12922 ± 0.00057 1.12920 13 3.30 3.302 13 109.50 13 a Expanded uncertainties U are U(η) = 0.01 mPa s, U(T)= 0.01 K, and U(p)= 10 kPa (0.95 level of confidence).…”
Section: Resultsmentioning
confidence: 99%
“…The details about viscometer have already been described earlier. 14 The viscosities were measured with an accuracy of ±1%.…”
Section: Introductionmentioning
confidence: 99%
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“…Viscosities of the experimental solution (η, mPas) were measured by Brookfield DV-III Ultra Programmable Rheometer having a spindle size-42 with an accuracy of ±1%. The particulars about the viscometer have previously been depicted earlier [15].…”
Section: Issn: 2394-5311mentioning
confidence: 87%
“…The K a (NBu 4 PF 6 ) value obtained is consistent with the data reported in the literature in acetonitrile 22 as well as those in other solvents of similar dielectric constant. 23 3.2.2. Square-Wave Voltammetry Study.…”
Section: Ion Pairing Between the Supporting Electrolyte Ionsmentioning
confidence: 99%