As one of the alternative insulation gases, C 4 F 7 N/CO 2 gas mixtures have attracted much attention recently. In this study, the normalized Townsend first ionization coefficient α/N and the normalized attachment coefficient η/N were measured in C 4 F 7 N/CO 2 gas mixtures by using the Steady-State Townsend (SST) method over a range of electric fields E/N from 100 to 550 Td. The concentrations of C 4 F 7 N studied were 4.99, 7.00, 9.00, 13.13 and 20.02%, and the gas pressure were 500 Pa at 20 • C. The effective ionization coefficients and the critical electric field were obtained at 500, 1000 and 2000 Pa to investigate the effect of gas pressure on dielectric strength in 9.00%C 4 F 7 N/91.00%CO 2 respectively. The results indicated that the (E/N) lim have not significant change on the SST experimental conditions. Meanwhile, a comparison with SF 6 gas indicates that 20.02% C 4 F 7 N/79.98% CO 2 has a similar insulation performance with (E/N) lim as 358.82 Td. However, when the liquefaction temperature is considered, the C 4 F 7 N/CO 2 gas mixtures with 9.00% C 4 F 7 N could be considered as an appropriate substitute gas for SF 6 , because the critical electric field of this gas mixture is over 70% of SF 6 gas and could be used under-15 • C at 0.7 MPa. INDEX TERMS C 4 F 7 N/CO 2 , ionization coefficient, attachment coefficient, critical electric field, steady-state Townsend method.