2016
DOI: 10.3390/ijms17030391
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Ionogels Based on Poly(methyl methacrylate) and Metal-Containing Ionic Liquids: Correlation between Structure and Mechanical and Electrical Properties

Abstract: Ionogels (IGs) based on poly(methyl methacrylate) (PMMA) and the metal-containing ionic liquids (ILs) bis-1-butyl-3-methlimidazolium tetrachloridocuprate(II), tetrachloride cobaltate(II), and tetrachlorido manganate(II) have been synthesized and their mechanical and electrical properties have been correlated with their microstructure. Unlike many previous examples, the current IGs show a decreasing stability in stress-strain experiments on increasing IL fractions. The conductivities of the current IGs are lowe… Show more

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Cited by 25 publications
(17 citation statements)
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“…Synthesis of all compounds was achieved using established and publishedp rotocols from commercial startingm aterials. [11] Figure 1s hows the general synthesis and the resulting ILs. All products are solids at room temperature, but melt between 60 and 93 8C.…”
Section: Resultsmentioning
confidence: 99%
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“…Synthesis of all compounds was achieved using established and publishedp rotocols from commercial startingm aterials. [11] Figure 1s hows the general synthesis and the resulting ILs. All products are solids at room temperature, but melt between 60 and 93 8C.…”
Section: Resultsmentioning
confidence: 99%
“…Consequently,M ILs have interesting electrochemical, magnetic, catalytic, and opticalp roperties, whichc annotb eo btained otherwise. [3,9,[11][12][13][14][15][16][17][18][19][20][21] Especially transition-metal-based MILs have attracted attention. This is, amongo thers, due to the fact MILs are not only interesting materials in their own right but can also act as ionic liquid precursors (ILPs)o r, as they are also termed, "all-in-one solventtemplate-reactants", [22] for the controlled synthesis of inorganic and hybrid materials.…”
Section: Introductionmentioning
confidence: 99%
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“…To the best of our knowledge, crystallographic investigations of imidazolium-based salts containing the [Mn II X 4 ] 2− ( X = halide) anions are only known for (ImH) 2 [MnCl 4 ]·(ImH) 4 [MnCl 6 ] (ImH = 1 H-imidazolium) [45], (MImPPy)[MnCl 4 ] (MImPPy = 1-(3-(1-Methylimidazolium-3-yl) propyl) pyridinium) and (DMBIm)[MnCl 4 ] (DMBIm = 1,1’-Butane-1, 4-diylbis (3-methylimidazolium) [46], (BMIm) 2 [MnCl 4 ] (BMIm = 1-Butyl-3-methylimidazolium) [47,48] and (BMIm) 2 [MnBr 4 ] [49], respectively. It is obvious that, until now, there has been no single crystal data available for imidazolium-based systems, which contain pseudohalides as ligands in the complex anion [Mn II (NCX) 4 ] 2− ( X = O, S).…”
Section: Introductionmentioning
confidence: 99%