Ionothermal synthesis of the Metal-Organic Framework compound Cu3(BTC)2

Liu, Lei; Wei, Haibo; Zhang, Lianyin; Li, Jinping; Dong, Jinxiang

doi:10.1016/s0167-2991(08)80240-6

Cited by 21 publications

(6 citation statements)

References 10 publications

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“…The accumulation of OH – may effectively increase the solubility of H 2 bdc and increase the reaction rate between metal cations and 1,4-benzenedicarboxylic acid carboxylate anions. Simultaneously, the formation of CO 3 2– might also facilitate the synthesis of Mn-doped MIL-53(Fe) . This shows that the addition of urea can improve the synthesis of the Mn-doped MIL-53(Fe) precursor.…”

Section: Resultsmentioning

confidence: 91%

MOF-Derived Hierarchical MnO-Doped Fe₃O₄@C Composite Nanospheres with Enhanced Lithium Storage

Wang

Zhu

et al. 2018

ACS Appl. Mater. Interfaces

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Hierarchically nanostructured binary/multiple transition-metal oxides with electrically conductive coatings are very attractive for lithium-ion batteries owing to their excellent electrochemical properties induced by their unique compositions and microstructures. Herein, hierarchical MnO-doped FeO@C composite nanospheres are prepared by a simple one-step annealing in Ar atmosphere, using Mn-doped Fe-based metal-organic frameworks (Mn-doped MIL-53(Fe)) as precursor. The MnO-doped FeO@C composite particles have a uniform nanosphere structure with a diameter of ∼100 nm, and each nanosphere is composed of clustered primary nanoparticles with an amorphous carbon shell, forming a unique hierarchical nanoarchitecture. The as-prepared hierarchical MnO-doped FeO@C composite nanospheres exhibit markedly enhanced lithium-storage performance, with a large capacity of 1297.5 mAh g after 200 cycles at 200 mA g. The cycling performance is clarified through analyzing the galvanostatic discharge/charge voltage profiles and electrochemical impedance spectra at different cycles. The unique microstructures and Mn element doping of the hierarchical MnO-doped FeO@C composite nanospheres lead to their enhanced lithium-storage performance.

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Section: Resultsmentioning

confidence: 91%

MOF-Derived Hierarchical MnO-Doped Fe₃O₄@C Composite Nanospheres with Enhanced Lithium Storage

Wang

Zhu

et al. 2018

ACS Appl. Mater. Interfaces

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“…Owing to the distinctive properties of ILs, viz. , high solvating potential, zero vapor pressure, extraordinary thermal stability, and feasible processability, IL has captured prominence as a solvent . Reportedly, 1-alkyl-3-methylimidazolium derivative ILs have been widely employed for MOF synthesis. , Additionally, reports of the utilization of deep eutectic mixtures with lower melting points compared to precursor materials are also available, which demonstrate certain benefits such as cost-effectiveness, easy preparation, and unreactivity to atmospheric moisture. , This method is employed to synthesize HUSK 1 utilizing chloride/dimethyl as a solvent .…”

Section: Trends In Mofsmentioning

confidence: 99%

Stimuli-Responsive Design of Metal–Organic Frameworks for Cancer Theranostics: Current Challenges and Future Perspective

Pantwalawalkar,

Mhettar,

Nangare

et al. 2023

ACS Biomater. Sci. Eng.

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Scientific fraternity revealed the potential of stimuli-responsive nanotherapeutics for cancer treatment that aids in tackling the major restrictions of traditionally reported drug delivery systems. Among stimuli-responsive inorganic nanomaterials, metal–organic frameworks (MOFs) have transpired as unique porous materials displaying resilient structures and diverse applications in cancer theranostics. Mainly, it demonstrates tailorable porosity, versatile chemical configuration, tunable size and shape, and feasible surface functionalization, etc. The present review provides insights into the design of stimuli-responsive multifunctional MOFs for targeted drug delivery and bioimaging for effective cancer therapy. Initially, the concept of cancer, traditional cancer treatment, background of MOFs, and approaches for MOFs synthesis have been discussed. After this, applications of stimuli-responsive multifunctional MOFs-assisted nanostructures that include pH, light, ions, temperature, magnetic, redox, ATP, and others for targeted drug delivery and bioimaging in cancer have been thoroughly discussed. As an outcome, the designed multifunctional MOFs showed an alteration in properties due to the exogenous and endogenous stimuli that are beneficial for drug release and bioimaging. The several reported types of stimuli-responsive surface-modified MOFs revealed good biocompatibility to normal cells, promising drug loading capability, target-specific delivery of anticancer drugs into cancerous cells, etc. Despite substantial progress in this field, certain crucial issues need to be addressed to reap the clinical benefits of multifunctional MOFs. Specifically, the toxicological compatibility and biodegradability of the building blocks of MOFs demand a thorough evaluation. Moreover, the investigation of sustainable and greener synthesis methods is of the utmost importance. Also, the low flexibility, off-target accumulation, and compromised pharmacokinetic profile of stimuli-responsive MOFs have attracted keen attention. In conclusion, the surface-modified nanosized design of inorganic diverse stimuli-sensitive MOFs demonstrated great potential for targeted drug delivery and bioimaging in different kinds of cancers. In the future, the preference for stimuli-triggered MOFs will open a new frontier for cancer theranostic applications.

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“…During 2000, DES have been used both as the solvent of the reaction and the source of the template (structure-directing agents); the so called-ionothermal synthesis. This strategy provided opportunities to develop new synthetic routes for the preparation of several organometallic chemicals [96][97][98][99][100][101].…”

Section: Des As Synthesis Media Of Natural Based Chemicalsmentioning

confidence: 99%

Applications of Deep Eutectic Solvents Related to Health, Synthesis, and Extraction of Natural Based Chemicals

et al. 2021

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Deep eutectic solvents are liquid mixtures of solid components at room temperature, which present exceptional properties: high solvent capacity, high biodegradation, low volatile organic compound character, and relatively low toxicity. Furthermore, there are an important number of DES described, formed by different components and ratios, and thus, the studied applications are also numerous. In this review, we focused on the applications related to health. One of the most promising applications of DES is the development of oral liquid formulations of poorly soluble active pharmaceutical ingredients, although it currently remains at an early stage. We have analyzed the potential and limitations of DES with this regard. Furthermore, DES have been used as synthesis media. In this work, we revised the use of DES to obtain bioactive natural products via synthesis or extraction process. Finally, the usefulness of DES in other interesting applications for promoting health has been also examined: this is the case of genomics studies, nano-carriers for the encapsulation of anticancer drugs or stabilization of samples for medical purposes.

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Ionothermal synthesis of the Metal-Organic Framework compound Cu3(BTC)2

Cited by 21 publications

References 10 publications

MOF-Derived Hierarchical MnO-Doped Fe₃O₄@C Composite Nanospheres with Enhanced Lithium Storage

MOF-Derived Hierarchical MnO-Doped Fe₃O₄@C Composite Nanospheres with Enhanced Lithium Storage

Stimuli-Responsive Design of Metal–Organic Frameworks for Cancer Theranostics: Current Challenges and Future Perspective

Applications of Deep Eutectic Solvents Related to Health, Synthesis, and Extraction of Natural Based Chemicals

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Ionothermal synthesis of the Metal-Organic Framework compound Cu3(BTC)2

Cited by 21 publications

References 10 publications

MOF-Derived Hierarchical MnO-Doped Fe3O4@C Composite Nanospheres with Enhanced Lithium Storage

MOF-Derived Hierarchical MnO-Doped Fe3O4@C Composite Nanospheres with Enhanced Lithium Storage

Stimuli-Responsive Design of Metal–Organic Frameworks for Cancer Theranostics: Current Challenges and Future Perspective

Applications of Deep Eutectic Solvents Related to Health, Synthesis, and Extraction of Natural Based Chemicals

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MOF-Derived Hierarchical MnO-Doped Fe₃O₄@C Composite Nanospheres with Enhanced Lithium Storage

MOF-Derived Hierarchical MnO-Doped Fe₃O₄@C Composite Nanospheres with Enhanced Lithium Storage