IR spectral manifestation of the association of organic liquids in a solid matrix

Гринвальд, И. И.; Kalagaev, I. Yu.; Artemov, A. N.; Sutyagina, E. A.; Spirin, I. A.

doi:10.1007/s11172-014-0480-3

Cited by 3 publications

(2 citation statements)

References 9 publications

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“…A short time ago we have presented the method, allowing to fix and stabilize similar intermediates in solid phase . In such a way different types of water complexes, which could not be observed by the other technique, were revealed and examined by IR spectroscopy.…”

Section: Introductionmentioning

confidence: 99%

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Water Complexes of Ionic Liquids: 1‐Butyl‐3‐methyl Imidazolium Chloride and Tetrafluoroborate Systems in KBr Matrix.

et al. 2017

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In the present work the formation of water complexes with ionic liquids (ILs) -1-butyl-3-methylimidazolium chloride [bmim][Cl] and 1-butyl-3-methylimidazolium tetrafluoroborate [bmim][BF 4 ] in KBr matrix at ambient temperature by IR technique was studied. There was shown that between the components of the system the hydrogen bond, in which the heteroaromatic fragment and anion (Cl À or BF 4 À ) can participate, arises. The ab initio calculation in terms of DFT predicts a possibility of an interaction between the hydrogen atoms of CH bond in heteroaromatic ring and CH 3 -group with oxygen atom as well as between anion (Cl À or BF 4 À ) with hydrogen atom of water molecule.

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Section: Introductionmentioning

confidence: 99%

“…In such a way different types of water complexes, which could not be observed by the other technique, were revealed and examined by IR spectroscopy. It was shown that both single water molecules and the mobile hydrogen atom of water clusters can participate in the coordination mechanism …”

Section: Introductionmentioning

confidence: 99%